螺旋等离子体-介电合使状核心外纳米颗粒能够产生强烈的近红外光学反应
Xiali Lv1,2, Yu Tian1, Fengxia Wu1
1State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China.
Nature communications
|October 25, 2024
概括
晶体等离子体-介电合使状金-铜氧化物纳米粒子具有可调节的近红外光学响应. 这一突破为先进的纳米光子和生物医学应用提供了增强的极化旋转.
科学领域:
- 塑制剂是一种塑制剂.
- 纳米材料科学 科学 纳米材料科学
- 奇拉性研究 奇拉性研究
背景情况:
- 螺旋体等离子体纳米粒子是具有可调节性质的人工性材料.
- 扩展近红外 (NIR) 范围对生物医学和纳米光子应用至关重要.
- 对于NIR应用而言,这种材料的合理设计仍然是一个重大挑战.
研究的目的:
- 提出并演示一种策略,用于利用合性等离子体-介电合来操纵光反应进入NIR区域.
- 设计和合成状金铜氧化物 (Au@Cu2O) 纳米粒子,具有增强的NIR手术特性.
- 为了实现高光学异构性,并探索在NIR区域的多频段手术行为.
主要方法:
- 采用 chiral 等离子体 - 介电合策略.
- 设计和合成状Au@Cu2O纳米粒子.
- 使用光谱和电磁模拟,包括多极扩张分析.
- 将偏振旋转能力与状金纳米粒子进行比较.
主要成果:
- 在状Au@Cu2O纳米粒子中实现了可调和和丰富的NIR手术反应.
- 在NIR区域获得0.35的高光学异构性 (g-因子).
- 观察到的多频段手术行为归因于强大的等离子体-介电合.
- 与状黄金纳米粒子相比,证明了增强的极化旋转能力.
结论:
- 嵌合体等离子体-介电合是一种有效的策略,可以实现具有高光学异构性的NIR光学反应.
- 电磁多极共振模式的相互作用驱动了观察到的手术现象.
- 螺旋体Au@Cu2O纳米粒子为需要NIR手术特性的先进纳米光子和生物医学应用提供了一个有前途的平台.
更多相关视频
08:54Performing Spectroscopy on Plasmonic Nanoparticles with Transmission-Based Nomarski-Type Differential Interference Contrast Microscopy
Published on: June 5, 2019
7.6K
09:29Utilization of Plasmonic and Photonic Crystal Nanostructures for Enhanced Micro- and Nanoparticle Manipulation
Published on: September 27, 2011
12.3K
相关概念视频
Chirality in Nature
13.0K
Chirality is the most intriguing yet essential facet of nature, governing life’s biochemical processes and precision. It can be observed from a snail shell pattern in a macroscopic world to an amino acid, the minutest building block of life. Most of the snails around the world have right-coiled shells because of the intrinsic chirality in their genes. All the amino acids present in the human body exist in an enantiomerically pure state, except for glycine - the sole achiral amino acid.
13.0K
¹H NMR: Long-Range Coupling
1.7K
The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene...
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene...
1.7K
Chirality
23.4K
Chirality is a term that describes the lack of mirror symmetry in an object. In other words, chiral objects cannot be superposed on their mirror images. For example, our feet are chiral, as the mirror image of the left foot, the right foot, cannot be superposed on the left foot.
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
23.4K
Chirality at Nitrogen, Phosphorus, and Sulfur
5.7K
Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
5.7K
NMR Spectroscopy: Spin–Spin Coupling
1.3K
The spin state of an NMR-active nucleus can have a slight effect on its immediate electronic environment. This effect propagates through the intervening bonds and affects the electronic environments of NMR-active nuclei up to three bonds away; occasionally, even farther. This phenomenon is called spin–spin coupling or J-coupling. Coupling interactions are mutual and result in small changes in the absorption frequencies of both nuclei involved. While nuclei of the same element are involved...
1.3K
Prochirality
3.8K
The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...
3.8K
