甘油碳酸盐作为轻型原油的乳化剂:合成,表征和稳定性分析
Ana Beatriz Morales Cepeda1, Elda Elizabeth Villalobos Neri2, Luis Alejandro Macclesh Del Pino Pérez1
1Centro de Investigación en Petroquímica, Tecnológico Nacional de México/Instituto Tecnológico de Cd. Madero, Altamira 89600, Mexico.
Molecules (Basel, Switzerland)
|October 26, 2024
概括
甘油碳酸盐 (GC) 有效地乳化轻型原油,形成稳定的乳液超过24小时. 这种环保的乳化剂对油污清理和石油回收应用的增强有前途.
科学领域:
- 绿色化学 绿色化学
- 材料科学 材料科学 材料科学
背景情况:
- 原油乳化对于各种工业过程至关重要,包括增强石油回收和泄漏整治.
- 开发环保和有效的乳化剂是石油行业的一个关键挑战.
研究的目的:
- 合成甘碳酸盐 (GC) 并评估其作为轻型原油乳化剂的性能.
- 在不同度下评估基于GC的乳液的稳定性和效率.
- 探索GC作为石油相关应用中的可持续替代品的潜力.
主要方法:
- 糖醇碳酸盐通过糖醇和二甲基碳酸盐的转化合成,达到90%的产量.
- 使用1H-NMR,13C-NMR和FT-IR光谱学进行结构性表征.
- 用轻型原油和水进行不同GC度 (60/40,70/30,80/20) 的乳化试验.
- 乳液稳定性和滴滴大小分析.
主要成果:
- 成功合成高产量和已确认结构的甘碳酸盐.
- GC证明了轻型原油的有效乳化,形成稳定的乳液超过24小时.
- 较高的GC度导致较小的滴滴大小,这表明乳化效率提高.
- 颗粒大小分析证实,随着GC度的增加,乳液稳定性得到了改善.
结论:
- 甘碳酸盐是轻型原油的高效和稳定的乳化剂.
- 它的生物降解性和低毒性使其成为环保的选择.
- 气体加热具有在石油泄漏整治和增强石油回收方面的巨大应用潜力.
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