使用FT-ICR MS在长江流域的自然和人为溶解有机物的表征
Cuiping Ning1, Shuai Sun2, Yuan Gao3
1School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China; Chinese Academy of Sciences, Dalian Institute of Chemical Physics, Dalian 116023, China.
Water research
|October 26, 2024
概括
科学家在长江盆地发现了数千个溶解有机物 (DOM) 分子,揭示了人类活动对水的组成的影响. 这项研究为水生生态系统中的自然和人为有机物提供了关键的见解.
科学领域:
- 环境化学环境化学
- 生物地质化学生物地质化学
- 分析化学 分析化学
背景情况:
- 溶解有机物 (DOM) 是一种复杂的混合物,对全球碳循环和气候至关重要.
- 了解DOM的化学成分是其生物地化学行为的关键,但分子识别很困难.
- 自然水中含有各种各样的有机分子,受到自然过程和人为投入的影响.
研究的目的:
- 开发和应用一个新的框架来研究自然水域的DOM特征.
- 识别单个DOM分子并量化自然与人为有机物的比例.
- 评估长江流域内DOM组成的空间变化.
主要方法:
- 采用了超高分辨率的里埃转换离子循环子子共振质谱法 (FT-ICR-MS).
- 开发并应用了用于分子公式分配的内部数据库.
- 分析了来自长江流域各个地点的DOM样本.
主要成果:
- 在长江流域的DOM分配了9006个明确的分子公式.
- 从上游到下游观察到CHNO和CHOS化合物的增加.
- 暂时确定了1099种DOM化合物:85%内源性 (如脂质) 和15%外源性 (如药品和个人护理产品).
结论:
- 人为排放显著增加了下游地区的DOM数量和丰度.
- 该研究揭示了人类活动对水生环境中DOM成分的重大影响.
- 开发的框架允许对DOM进行详细的描述,区分自然和人为来源.
相关概念视频
High-Performance Liquid Chromatography: Types of Detectors
2.3K
The role of the detectors in High-Performance Liquid Chromatography (HPLC) is to analyze the solutes as they exit from the chromatographic column. The detector recognizes the solute's property and generates corresponding electrical signals, which are converted into a readable graph of the detector's response versus elution time called a chromatogram at the computer. There are several types of HPLC detectors, each with its own advantages and limitations, depending on the analyte...
2.3K
Ion-Exchange Chromatography
3.0K
Ion-exchange chromatography, or IEC, is a technique for separating ions based on their affinity for the stationary phase. The stationary phase is a cross-linked polymer resin with covalently attached ionic functional groups. The functional groups can be either positively charged (cation exchangers) or negatively charged (anion exchangers). A cation exchanger consists of a polymeric anion and active cations, while an anion exchanger is a polymeric cation with active anions. The choice of...
3.0K


