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相关概念视频

Isothermal Processes01:21

Isothermal Processes

3.6K
A thermodynamic process that occurs at constant temperature is called an isothermal process. Heat slowly flows into the system or out of the system to maintain thermal equilibrium. Processes involving phase changes like water evaporation into steam or freezing water into ice at a constant temperature are examples of Isothermal Processes.
An ideal gas can also undergo isothermal expansion or compression.
For example, consider 1 mole of an ideal gas inside an isolated cylinder at initial volume V...
3.6K
Adiabatic Processes for an Ideal Gas01:18

Adiabatic Processes for an Ideal Gas

3.0K
When an ideal gas is compressed adiabatically, that is, without adding heat, work is done on it, and its temperature increases. In an adiabatic expansion, the gas does work, and its temperature drops. Adiabatic compressions actually occur in the cylinders of a car, where the compressions of the gas-air mixture take place so quickly that there is no time for the mixture to exchange heat with its environment. Nevertheless, because work is done on the mixture during the compression, its...
3.0K
Calculating Standard Free Energy Changes02:49

Calculating Standard Free Energy Changes

20.7K
The free energy change for a reaction that occurs under the standard conditions of 1 bar pressure and at 298 K is called the standard free energy change. Since free energy is a state function, its value depends only on the conditions of the initial and final states of the system. A convenient and common approach to the calculation of free energy changes for physical and chemical reactions is by use of widely available compilations of standard state thermodynamic data. One method involves the...
20.7K
Path Between Thermodynamics States01:21

Path Between Thermodynamics States

3.1K
Consider the two thermodynamic processes involving an ideal gas that are represented by paths AC and ABC in Figure 1:
3.1K
Standard Entropy Change for a Reaction03:00

Standard Entropy Change for a Reaction

19.8K
Entropy is a state function, so the standard entropy change for a chemical reaction (ΔS°rxn) can be calculated from the difference in standard entropy between the products and the reactants.
19.8K
Heating and Cooling Curves02:44

Heating and Cooling Curves

22.7K
When a substance—isolated from its environment—is subjected to heat changes, corresponding changes in temperature and phase of the substance is observed; this is graphically represented by heating and cooling curves.
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
22.7K

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Spin Saturation Transfer Difference NMR SSTD NMR: A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes
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Spin Saturation Transfer Difference NMR SSTD NMR: A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes

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吸附热力学用于过程模拟.

Usman Hamid1, Chau-Chyun Chen1

  • 1Department of Chemical Engineering, Texas Tech University, Lubbock, Texas 79409-3121, United States.

Langmuir : the ACS journal of surfaces and colloids
|October 28, 2024
PubMed
概括

本研究介绍了吸附平衡的概括热力学模型,克服了现有方法的局限性. 这些新模型提高了预测多组分吸附的准确性,减少了对工业应用的昂贵试点研究的依赖.

科学领域:

  • 热力学是一种热力学.
  • 化学工程是化学工程的重要组成部分.
  • 材料科学 材料科学 材料科学

背景情况:

  • 吸附是工业中至关重要的分离技术,但对多组件系统的严格热力学建模仍然是一个挑战.
  • 目前的模型,如扩展的朗穆尔和吸附解决方案理论有局限性,迫使人们依赖昂贵的试点研究来开发过程.

研究的目的:

  • 强调需要先进的吸附热力学模型,并批评现有的模型.
  • 为准确的多元组件吸附平衡预测提供概括的朗穆尔和布鲁纳uer-Emmett-Teller等热量.

主要方法:

  • 导出了一个活性系数模型,以考虑吸附剂-吸附剂相互作用.
  • 通过将度替换为多组件系统的活动来概括经典的同温度.
  • 扩展模型用于单层和多层吸附场景.

主要成果:

  • 开发了通用的兰格穆尔和布鲁纳uer-Emmett-Teller等热体,需要最小的,物理上有意义的参数.
  • 这些模型有效地解决了吸附剂表面异质性,度,非理想性和多层吸附.
  • 已证明能够预测吸附性亚热形成的能力.

结论:

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  • 一般化模型为吸附平衡的热力学建模提供了更严格,更准确的方法.
  • 高质量,全面的吸附数据对于可靠的模型参数确定和过程优化至关重要.
  • 这些进展可以显著减少在开发吸附装置方面进行广泛试点研究的需要.