巨大的增强和快速稳定电容在抗铁电的相位过渡工程的电容
Tengfei Hu1,2, Zhengqian Fu3, Xiaowei Liu1
1State Key Laboratory of High Performance Ceramics and Superfine Microstructures & The Key Lab of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China.
Nature communications
|October 29, 2024
概括
在临界值附近应用脉冲电场可以增强抗铁电陶. 这种相位过渡工程策略通过诱导结构演变和稳定调制结构来提高电容密度.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 陶工程 陶工程 陶工程
背景情况:
- 反铁电-铁电相位过渡是高电容密度非线性电容器的关键.
- 目前属性优化依赖于化学成分定制,限制了创新.
- 需要一种新的方法来增强抗铁电陶的性能.
研究的目的:
- 提出并研究使用脉冲电刺激的相位过渡工程战术.
- 为了增强和稳定Pb$_{0.97}$La$_{0.02}$(Zr$_{0.35}$Sn$_{0.55}$Ti$_{0.10}$) O$_{3}$抗铁电陶的电容密度.
- 了解由电刺激引起的结构进化.
主要方法:
- 在临界电场附近应用脉冲电刺激.
- 现场和现场结构特征 (例如,X射线衍射).
- 分析结构与属性的相关性.
主要成果:
- 实现了~54.3%的增强和电容密度的快速稳定.
- 观察到的电刺激诱导了连续的结构进化:域变化 (多域到单域) 和调制周期转移 (7.49到7.73).
- 确定模块化结构的不可逆转回收作为财产增强的主要机制.
结论:
- 脉冲电刺激为优化抗铁电特性提供了一种可行的替代化学定制方法.
- 这种相位过渡工程加深了对不相称的反铁电的结构过渡的理解.
- 这些发现使先进材料和设备的组成独立的后处理性质创新成为可能.
相关概念视频
Dielectric Polarization in a Capacitor
4.6K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
4.6K
MOS Capacitor
711
A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
711
Capacitor With A Dielectric
3.9K
Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
3.9K
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Capacitors
416
Capacitors play a crucial role in car radios, where they filter and store frequencies to ensure clear signal reception. Essentially serving as energy storage devices, capacitors store energy within their electric field and are composed of two parallel conducting plates separated by a dielectric.
When a voltage source is connected to a capacitor, positive and negative charges accumulate on the opposite plates. This accumulation generates a potential difference that equals the product of the...
When a voltage source is connected to a capacitor, positive and negative charges accumulate on the opposite plates. This accumulation generates a potential difference that equals the product of the...
416
Capacitors and Capacitance
7.5K
A device consisting of two electrical conductors that are separated by a distance and used to store electrical charges is called a capacitor. The space between the conductors is either a vacuum or an insulating material, called a dielectric. Capacitors have many applications, ranging from filtering static from radio reception to energy storage in heart defibrillators.
When the conductors are two identical parallel plates, it is called a parallel plate capacitor. When battery terminals are...
When the conductors are two identical parallel plates, it is called a parallel plate capacitor. When battery terminals are...
7.5K


