影响第一阶段过渡的残余铁磁区域在非静态铁-中
Alex Aubert1, Konstantin Skokov1, Andrei Rogalev2
1Functional Materials, Institute of Material Science, Technical University of Darmstadt, 64287 Darmstadt, Germany.
ACS applied materials & interfaces
|October 29, 2024
概括
铁体积测量对其第一阶段过渡 (FOPT) 特性产生了重大影响. 即使是微小的铁 (Fe) 过量也可以抑制FOPT,影响磁热性能并揭示残留铁磁域的作用.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 磁力学 磁力学 是一种
背景情况:
- 由于其简单的结构和显著的磁热效应,FeRh是研究第一阶段过渡 (FOPT) 的参考材料.
- 理论研究表明,Fe/Rh固体测量接近原子组合强烈影响FOPT特征,但实验验证有限.
研究的目的:
- 实验性地研究组合对FeRh.中的过渡性歇斯底里和FOPT行为的影响.
- 了解在FeRh.中负责FOPT的静脉测量灵敏度的潜在机制.
主要方法:
- 研究的FeRh样本具有不同的Fe/Rh静脉测量.
- 利用特定元素的X射线磁圆二元化 (XMCD) 来识别铁磁贡献.
- 采用Mössbauer光谱检测Fe的抗体缺陷.
主要成果:
- 过多的Fe1at.%诱导了样本的一小部分的铁磁状态,而5at.%完全消除了FOPT.
- XMCD显示了残留FeRh铁磁区域的铁磁贡献.
- 莫斯巴乌尔光谱学证实了Rh位点上Fe原子的存在 (Fe反位点缺陷).
结论:
- 在FeRh的固态度偏差显著改变FOPT的特性和磁热性能.
- 铁抗体缺陷负责残余铁磁域的形成,影响FOPT的行为.
- 这项研究阐明了FeRh中FOPT的稳定测量灵敏度,这对理解FOPT动态和铁磁域作用有意义.
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