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相关概念视频

X-ray Diffraction of Biological Samples01:10

X-ray Diffraction of Biological Samples

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X-ray diffraction or XRD is an analytical tool that utilizes X-rays to study ordered structures such as crystalline organic and inorganic samples, polycrystalline materials, proteins, carbohydrates, and drugs.
According to Bragg's law, when X-rays strike the sample positioned on a stage, the rays are  scattered by the electron clouds around the sample atoms. The  X-ray diffraction or scattering is caused by constructive interference of the X-ray waves that reflect off the internal...
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Scanning Electron Microscopy01:07

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A scanning electron microscope (SEM) is used to study the surface features of a sample by using an electron beam that scans the sample surface in a two-dimensional manner. Typically, areas between ~1 centimeter to 5 micrometers in width can be imaged. SEM can be used to image bacteria, viruses, tissues as well as larger samples like insects. Conventional SEM gives a magnification ranging from 20X to 30,000X and spatial resolution of 50 to 100 nanometers.
Fundamental Principles
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Atomic Emission Spectroscopy: Overview01:20

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Atomic emission spectroscopy (AES) is an analytical technique used to determine the elemental composition of a sample by analyzing the light emitted from excited atoms. In AES, atoms in a sample are excited to higher energy levels by thermal energy from high-temperature sources, such as plasma, arcs, or sparks. When these excited atoms return to lower energy states, they emit light at specific wavelengths characteristic of each element. The resulting atomic emission spectrum, which consists of...
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NMR Spectrometers: Resolution and Error Correction01:14

NMR Spectrometers: Resolution and Error Correction

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When magnetic nuclei in a sample achieve resonance and undergo relaxation, the signal detected in NMR is an approximately exponential free induction decay. Fourier transform of an exponential decay yields a Lorentzian peak in the frequency domain. Lorentzian peaks in an NMR spectrum are defined by their amplitude, full width at half maximum, and position, where the peak width is governed by the spin-spin relaxation time alone. In real experiments, however, the applied magnetic field is rendered...
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Synchrotron X-ray Microdiffraction and Fluorescence Imaging of Mineral and Rock Samples
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对于X射线光谱显微镜的最佳稀有能量采样:使用模型减少顺序来减少X射线剂量和实验时间.

Paul D Quinn1, Malena Sabaté Landman2, Tom Davis3

  • 1Scientific Computing, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Campus, Didcot OX11 0QX, United Kingdom.

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概括
此摘要是机器生成的。

一种新的离散实证插值方法通过智能分样数据优化X射线光谱显微镜. 这种方法可以减少X射线剂量和测量时间,用于催化,环境和生物研究中的化学状态成像.

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科学领域:

  • 科学成像科学成像
  • 化学分析 化学分析
  • 频谱学是一种光谱学.

背景情况:

  • 在各种领域,X射线光谱显微镜对于化学状态成像至关重要.
  • 目前的限制包括缓慢的测量速度,稀释样品,辐射损伤和热漂移.
  • 这些因素阻碍了精确的化学状态分析.

研究的目的:

  • 开发一种更快,更准确的X射线光谱显微镜的方法.
  • 为了减少辐射剂量和测量时间的影响.
  • 为了改善化学状态变化的成像.

主要方法:

  • 采用了减少顺序模型方法:离散实证插值方法.
  • 最佳分样的光谱信息,考虑背景信号变化.
  • 利用先前的信息来指导采样和减少要求.

主要成果:

  • 从采样数据中获得了完全光谱测量的准确近似值.
  • 显著减少了总X射线剂量和获取时间.
  • 证明了该方法对各种光谱和光谱显微镜测量的适用性.

结论:

  • 离散的实证插值方法提高了X射线光谱显微镜的效率和准确性.
  • 这种方法在很大程度上可以适应低级近似的光谱测量.
  • 它为克服化学状态成像当前局限性的可行解决方案.