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Updated: Jun 9, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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过渡金属/兰化物-双键在碳中共同稳定

Zhanxin Jiang1, Ziqi Hu1, Yang-Rong Yao1

  • 1Key Laboratory of Precision and Intelligent Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China.

Precision chemistry
|October 30, 2024
PubMed
概括

这项研究报告了首次在单个富勒烯内同时稳定过渡金属-和甲双键. 这种独特的集群烯,TiCeN@C84,展示了新的结合和电子特性.

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In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
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