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Updated: Jun 9, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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与风车架构相结合的N-异环替代的Hexaperi-Hexabenzocoronenes与N-异环替代的Hexabenzocoronenes

Sven Mörsel1,2, Christian L Ritterhoff3, René Kellner1

  • 1Department of Chemistry and Pharmacy, Friedrich-Alexander-Universität Erlangen-Nürnberg, Nikolaus-Fiebiger-Str.10, 91058, Erlangen, Germany.

Chemistry (Weinheim an der Bergstrasse, Germany)
|October 30, 2024
PubMed
概括

研究人员合成了N-异环环替代的六次--enzocoronenes (HBCs),并发现替代物类型不会改变光电子特性. 多个英多尔替代剂因它们的排列而导致光谱变化和独特的符合性.

关键词:
合规性分析是指对合规性的分析.化物是一种化物.赫克萨班佐可罗烯是一种微波化学的微波化学其他N-异环环.

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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This lesson discusses the stability of substituted cyclohexanes with a focus on energies of various conformers and the effect of 1,3-diaxial interactions.
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