将MSWI飞灰转化为低碳和高兼容性复合材料,通过设计的硫氨酸基结合剂
Yan Xia1, Yading Zhao2, Atabaev F Baxtiyarovich3
1State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, China.
Journal of environmental management
|October 30, 2024
概括
本研究介绍了一种低碳粘合剂 (PCG),用于稳定危险废物,有效地固定有毒元素,与传统方法相比,减少60%的碳排放.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 城市固体废物焚烧飞灰 (MSWI FA) 是一种危险废物,需要有效的稳定/固化 (S/S).
- 现有的S/S方法往往缺乏环境可持续性和在固定潜在有毒元素 (PTE) 中的效率.
研究的目的:
- 开发一种低碳,高兼容性三元结合剂 (PCG) 用于MSWI FA稳定.
- 研究PCG结合剂和PTE (Pb, Cr) 之间的相互作用机制.
- 评估基于PCG的S/S块的环境和机械性能.
主要方法:
- 开发一种三元粘合剂 (PCG),使用硫酸水泥,普通波特兰水泥和颗粒高炉渣.
- 使用X射线衍射和侵入试验对粘合剂-PTE相互作用的研究.
- 评估S/S块的机械性能和透性.
- 用于碳排放分析的生命周期评估 (LCA).
主要成果:
- PCG结合剂通过对--酸盐-酸盐 (C-A-S-H) 阶段和酸盐产品的协同作用来增强PTE固定.
- 像Pb这样的PTE被C-A-S-H通过表面复合捕获,而Cr则被酸盐产品进一步固定.
- 基于PCG的S/S块表现出令人满意的机械强度 (>20MPa) 和低的PTE透性.
- 与普通波特兰水泥相比,LCA证实碳排放量减少了60%.
结论:
- 开发的PCG粘合剂对MSWI FA的低碳S/S有效,提供了增强的PTE固定.
- 该研究推进了危险废物的S/S方法,强调了低碳结合剂对环境的好处.
- PCG粘合剂为MSWI FA管理提供了可持续的解决方案,满足了低碳建筑材料的标准.
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