在一个大河流盆地,解开对长期缩的合水文和地化学控制
Ying Liang1,2, Rui Ma1,2, Henning Prommer3
1Hubei Key Laboratory of Yangtze River Basin Environmental Aquatic Science, School of Environmental Studies, China University of Geosciences, Wuhan 430074, China.
Environmental science & technology
|October 31, 2024
概括
沉积物 (NH4+) 通过阴离子交换而脱离,而不是有机物,驱动水体中的增加. 水文变化释放储存的氨,作为长期源.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 水文学的水文学
背景情况:
- 尽管农业N投入减少,但水体中的全球 (N) 度正在增加.
- 了解N运输机制对于管理水质至关重要.
研究的目的:
- 研究控制 (N) 反应运输和质量预算的过程.
- 了解长江流域在动态水文条件下的N动态.
主要方法:
- 长期的水地化学和液压监测.
- 溶解有机物 (DOM) 的分子特征.
- 列实验和反应式运输建模.
主要成果:
- 通过阴离子交换从沉积物中吸附氨 (NH4+) 是N动员的主要驱动因素.
- 有机化合物的矿化在释放中起不大作用.
- 反应性运输建模证实,由水文变化诱导的阴离子交换反应是释放N的关键.
结论:
- 沉积物中的离子交换作为历史N储存机制.
- 由于水文变化导致沉积物结合的NH4+的延迟脱落,作为长期的N来源.
- 水文变异性显著影响近地表沉积物中的NH4+分离.
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