通过流量空气采样器的采样效率:采样速率的影响
Qiu-Liang Cai1, Lei Tong2, Ning Zhong3
1Guangxi Key Laboratory of Urban Water Environment & Key Laboratory of Guangxi Universities in Ecological Environment Analysis and Pollution Control in the Western Guangxi, Baise University, Baise 533000, China; Key Laboratory of Urban Environment and Health & Ningbo Observation and Research Station, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China.
在收集空气污染物的过程中,通过流量采样器 (FTS) 的性能取决于风速. 较高的风速对挥发性化合物的影响更大,同时影响不那么挥发性化合物的突破量. 这项研究预测了用于准确大气监测的收集效率.
科学领域:
- 环境科学 环境科学
- 分析化学 分析化学
- 大气化学 大气化学
背景情况:
- 通过流量采样器 (FTS) 是一个以风力驱动的设备,用于收集空气样本.
- 在FTS的采样率波动需要了解它们对污染物突破的影响.
- 调查采样参数对FTS收集效率的影响对于准确的环境监测至关重要.
研究的目的:
- 通过使用FTS-PUF采样列,调查采样速率 (风速) 对PCB,PAH和OCP的突破概况的影响.
- 为了确定风速,化合物挥发率和采样柱效率 (理论板和突破体积) 之间的关系.
- 在不同的环境条件下开发FTS收集性能的预测模型.
主要方法:
- 相互连接的FTS采样柱,有三个以五种不同的采样速率 (风速) 运行,在293K和303K.
- 分析了多双 (PCB),多环芳 (PAH) 和有机杀虫剂 (OCP) 的突破性资料.
- 采用多重线性回归和线性溶解能量关系 (LSER) 分析来关联参数.
主要成果:
- 理论板的数量 (N) 和突破体积的对数 (logVB) 显示了与风速 (1/u) 的反向线性关系.
- 复合物挥发性影响了风速对N的影响;挥发性PCB受到影响最大.
- 风速对较不易挥发的化合物的突破体积的影响更大,与化合物挥发率 (logPL) 有显著的相关性.
结论:
- 建立了一个预测模型,将N和logVB与温度和风速相关联 (log(VB/m3) =2010/(T/K) -0.00066/(u/(m/s)) +0.55N-5.41).
- 在不同的温度和采样速率下,可以预测FTS-PUF采样柱的性能.
- 这为准确监测大气有机污染物度提供了有价值的数据.
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