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Updated: Jun 8, 2025

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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Published on: July 17, 2020

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大和长期的光子能量储存在diazetidines通过 [2+2]光环添加

Han P Q Nguyen1, Anurag Mukherjee1, Junichi Usuba1

  • 1Department of Chemistry, Brandeis University 415 South Street Waltham MA 02453 USA gracehan@brandeis.edu.

Chemical science
|November 1, 2024
PubMed
概括

通过循环添加,新的基沙通过循环添加储存超过300 J g-1的太阳能. 这些分子太阳能热系统提供长期存储和触发能量释放,推进能源解决方案.

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the...
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