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相关概念视频

Ions and Ionic Charges03:27

Ions and Ionic Charges

66.3K
In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called...
66.3K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.2K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.2K
Periodic Classification of the Elements04:00

Periodic Classification of the Elements

45.1K
The periodic table arranges atoms based on increasing atomic number so that elements with the same chemical properties recur periodically. When their electron configurations are added to the table, a periodic recurrence of similar electron configurations in the outer shells of these elements is observed. Because they are in the outer shells of an atom, valence electrons play the most important role in chemical reactions. The outer electrons have the highest energy of the electrons in an atom...
45.1K
Halogens03:01

Halogens

18.3K
Group 17 elements, known as halogens, are nonmetals. At room temperature, fluorine and chlorine are gases, bromine is a liquid, and iodine a solid. Astatine is a highly unstable radioactive element, so currently, most of its properties are unknown due to its short half-life. Tennessine is a synthetic element also predicted to be in this group. 
18.3K
Ionic Radii03:10

Ionic Radii

27.5K
Ionic radius is the measure used to describe the size of an ion. A cation always has fewer electrons and the same number of protons as the parent atom; it is smaller than the atom from which it is derived. For example, the covalent radius of an aluminum atom (1s22s22p63s23p1) is 118 pm, whereas the ionic radius of an Al3+ (1s22s22p6) is 68 pm. As electrons are removed from the outer valence shell, the remaining core electrons occupying smaller shells experience a greater effective nuclear...
27.5K
The Periodic Table03:25

The Periodic Table

77.6K
As early chemists discovered more elements, they realized that various elements could be grouped by their similar chemical behaviors. One such grouping includes lithium (Li), sodium (Na), and potassium (K). All of these elements are shiny, conduct heat and electricity well, and have similar chemical properties. A second grouping includes calcium (Ca), strontium (Sr), and barium (Ba), which also are shiny, good conductors of heat and electricity, and have chemical properties in common. However,...
77.6K

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相关实验视频

Updated: Jun 8, 2025

The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique
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The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique

Published on: November 28, 2016

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阴离子组13和14元素集群元素集群

Antoine Barthélemy1, Ingo Krossing1

  • 1Institut für Anorganische und Analytische Chemie and Freiburg Materials Research Center FMF, Albert-Ludwigs-Universität Freiburg, Albertstraße 21, 79104 Freiburg i.Br., Germany.

Inorganic chemistry
|November 1, 2024
PubMed
概括

最近对弱协调性离子的研究进展使得新型的第13组和第14组阴离子团的合成成为可能. 这些化合物表现出独特的结构,并且在键激活化学中表现出有希望.

科学领域:

  • 无机化学 无机化学 有机化学
  • 主组 元素化学 主组 元素化学

背景情况:

  • 13和14组元素的阳离子和中性集群已经很成熟. 弱协调性离子的发展最近促进了对阴离子集群化合物的获取.
  • 对第13组和第14组阴离子集群的研究是一个快速增长的研究领域.

研究的目的:

  • 提供关于第13组和第14组阴离子集群化合物的研究领域的全面概述.
  • 突出这些阴离子星团的不寻常结构和键激活应用.

主要方法:

  • 关于第13组和第14组阴离子团的合成和表征的最新文献的综述.
  • 讨论集群形成的挑战和合适的起始材料.

主要成果:

  • 已知的第13组和第14组阴离子集群化合物的数量显著增加.
  • 这些阴离子集群往往表现出独特的结构图案.
  • 已经证明了在键激活化学中的应用.

结论:

  • 13和14组的阴离子集群代表了主要组化学的一个令人兴奋的领域.
  • 它们不寻常的结构和反应性为新的化学转化提供了潜力.
  • 进一步研究它们的合成,结构和应用是有必要的.

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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV

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相关实验视频

Last Updated: Jun 8, 2025

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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
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