在TEMPO氧化纤维素中化碳基团,以改善TEMPO-CNC的表面水和热稳定性
Yuki Yoshikawa1, Kyohei Yamato1, Akiko Ishida2
1R&D Performance Chemicals Research, Kao Corporation, 1334 Minato, Wakayama 640-8580, Japan.
这项研究开发了一种具有成本效益的方法来化纤维素纳米材料 (CNs),显著提高其热稳定性. 该过程产生适用于高性能纳米复合材料的化CN.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 纳米技术 纳米技术
背景情况:
- 表面疏水的纤维素纳米材料 (CNs) 对于像环氧纳米复合材料这样的先进材料至关重要,需要高的热降解点.
- 化是水友性CN的关键修改,但高化比率的高效实现仍然是工业可扩展性的挑战.
- 目前的方法在CN中丰富的碳氧基组的有效功能化方面扎.
研究的目的:
- 为纤维素纳米材料开发一种高效,具有成本效益的化策略.
- 用于制备具有增强热稳定的表面疏水性CNs.
- 为了证明化纸质的转化为化纤维素纳米晶体的透明分散.
主要方法:
- 富含碳氧基的纤维木质纸是通过部分酸性水解制备的.
- 在DMF中使用聚烯糖醇-NH2和八胺与特定的凝结试剂和激活剂进行了异质固体/液体化.
- 使用高压均化,化纸质被加工成化纤维素纳米晶体的透明分散物.
主要成果:
- 在木质纸中实现了88%和91%的高化比,用于木质纸中的碳氧基.
- 显著增加了纤维素纳米材料的热降解点,从224°C提高到250°C以上.
- 成功地产生了氨基化纤维素纳米晶体的透明分散.
结论:
- 开发的异质化方法对于制备具有高热稳定性的表面疏水纤维素纳米材料是有效的.
- 这种方法为修改CN的工业应用提供了一个可扩展和具有成本效益的途径.
- 由此产生的氨基化CN是高性能纳米复合材料的合适前体.
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