Pt1Ni1@Pt/C核心外催化剂的碳固定合成,用于稳定的氧降解反应
Jialin Cui1, Di Zhang2, Zhongliang Liu1
1Key Laboratory for Ultrafine Materials of Ministry of Education, School of Chemical Engineering, East China University of Science and Technology, Shanghai, China.
高稳定的-核心外纳米粒子是使用新的碳缺陷定策略开发的,用于质子交换膜燃料电池. 这些催化剂具有出色的耐用性和高活性,用于氧降解反应.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 催化剂是一种催化剂.
背景情况:
- 质子交换膜燃料电池 (PEMFC) 需要高效的催化剂来进行氧减少反应 (ORR).
- 核心外纳米结构有效地最大限度地利用了催化剂中的贵金属.
- 开发稳定且高度活跃的ORR催化剂对于推进燃料电池技术至关重要.
研究的目的:
- 开发一种可控的"碳缺陷定"策略,用于制备高效和稳定的Pt-Ni核心外催化剂.
- 为ORR研究合成的Pt1Ni1@Pt/C纳米颗粒的结构稳定性和催化性能.
- 用一个全面的微动力学模型来验证实验发现.
主要方法:
- 合成Pt1Ni1@Pt/C核心外纳米粒子 (~2.6 nm) 在现场转换的缺陷碳支上,使用"碳缺陷定"策略.
- 催化剂的电化学表征,包括氧降解反应 (ORR) 的质量活性和特定活性测量.
- 经过7万个潜在周期的耐用性测试,并将实验结果与理论微动力学模型进行比较.
主要成果:
- 合成的Pt1Ni1@Pt/C纳米颗粒表现出极好的稳定性,由于强大的Pt-C相互作用,在7万个潜在周期后仅有1.6%的降解.
- 催化剂在0.9V时实现了高ORR质量活性 (1.424±0.019A/mgPt) 和特异性活性 (1.554±0.027mA/cmPt2) .
- 实验结果与综合微动力学模型的预测有很好的一致性,证实了它的准确性.
结论:
- "碳缺陷定"策略有效地为PEMFCs生产稳定且高度活性的Pt-Ni核心催化剂.
- 强大的Pt-C相互作用是防止纳米粒子聚合和确保催化剂耐用性的关键.
- 这项工作表明了理论建模和实验合成之间的成功协同作用,用于先进的催化剂设计.
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