使用素作为生物固化剂来设计完全基于生物的环氧化天然/聚乳性热塑性火化物,具有机械强度和多刺激响应形状记忆特性
Jiarong Huang1, Haonan Wu1, Xiao Wang1
1School of Mechanical and Automation Engineering, Wuyi University, Jiangmen 529020, China; Jiangmen Key Laboratory of Polymer Intelligent Manufacturing at Wuyi University, Wuyi University, Jiangmen 529020, China.
International journal of biological macromolecules
|November 3, 2024
概括
这项研究引入了素 (TA) 作为生物基固化剂,用于多乳酸/氧化天然热塑性火化物 (PLA/ENR TPVs). 这些可持续材料具有强大的机械性能和多刺激响应形状记忆,用于先进的执行器应用.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 可持续材料 可持续材料
背景情况:
- 对可持续聚合物的需求不断增长,以减轻碳排放.
- 需要从生物巨分子中获得的功能性材料.
- 传统的石油基聚合物的限制.
研究的目的:
- 开发完全基于生物的热塑性化物 (TPVs),使用素作为固化剂.
- 设计具有增强机械强度和多刺激响应形状记忆性能的TPV.
- 探索基于素的TPV在执行器应用中的潜力.
主要方法:
- 使用素 (TA) 作为多乳酸 (PLA) 和环氧化天然 (ENR) 的生物固化剂.
- 在ENR阶段内构建了一个双重交叉连接网络 (共价键和键).
- 实现了共同连续的形态,以改善界面应力传递.
主要成果:
- 成功制造出完全生物基的PLA/ENRTPV,具有出色的机械性能.
- 由各种刺激引发的多刺激响应形状记忆行为.
- 观察到光热对近红外光和阳光的响应,用于无接触的形状恢复.
- 由于共同连续的形态学,实现了平衡的刚性-性和形状记忆性能.
结论:
- 坦宁是一种有效的生物基固化剂,用于创建可持续的TPV.
- 开发的PLA/ENRTPV具有理想的机械和形状记忆性能.
- 色素的光热效应使先进的执行器功能成为可能,突出了它们在智能材料中的潜力.
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