在不同度的HCl下,对页岩成分变化对孔隙结构和碎形特征的影响的实验调查
Zepeng Sun1, Qipan Liu1, Lin Gan1
1College of Resources and Environment, Shanxi Agricultural University, Taigu 030801, China.
ACS omega
|November 4, 2024
概括
盐酸 (HCl) 处理改善了页岩水库的孔隙结构和气体生产. 这项研究表明,矿物质组成和酸度显著改变孔隙系统和碎形尺寸,为酸破裂策略提供了洞察力.
科学领域:
- 石油地质科学 石油地质科学
- 储水库工程 储水库工程
- 地质化学 地质化学
背景情况:
- 酸化是低透性页岩水库的关键刺激方法.
- 页岩气的生产受孔结构和矿物成分的影响.
- 盐酸 (HCl) 处理改变了页岩孔隙系统.
研究的目的:
- 研究页岩矿物质组成对孔隙结构和HCl处理后的碎形特征的影响.
- 确定不同度的酸盐如何影响页岩孔系统.
- 提供各种页岩水库的酸性压裂的理论参考.
主要方法:
- 对碳酸盐丰富,中等和贫乏的页岩进行实验,含有不同度的HCl (1,5,10重 %).
- 使用X射线衍射 (XRD) 进行矿物学分析.
- 采用低温吸附和碎形理论来分析孔隙结构和复杂性.
主要成果:
- 液化处理有效地减少了碳酸盐矿物质,溶解随着酸度的增加而增加.
- 在碳酸盐丰富/中等页岩中,中型和大型石增加;在碳酸盐贫乏页岩中,微型和中型石增加.
- 毛孔总体积 (TPV) 和总特定表面积 (TSSA) 在不同程度上增加.
- 碎形尺寸 (孔隙表面粗度D1和结构复杂性D2) 显示了对HCl度的成分依赖的反应.
结论:
- 页岩矿物学决定了在HCl处理下孔隙结构的演变.
- 优化HCl度和理解矿物学对于有效的页岩气刺激至关重要.
- 这些发现为在异质页岩储库中定制酸性压裂设计提供了宝贵的见解.
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