在混合的Sn-Pb化矿中产生氧气诱导的光增强兴奋剂
Jasmeen Nespoli1, Matthijs Mugge1, Lara M van der Poll1
1Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, 2629 HZ Delft, The Netherlands.
Journal of the American Chemical Society
|November 4, 2024
概括
暴露在氧气中会导致锡化的化,影响太阳能电池的性能. 这种氧气诱导的兴奋剂会导致锡的氧化和形成孔隙,损害电荷载体的动态,并导致长期的降解.
科学领域:
- 材料科学
- 太阳能发电
- 固态化学
背景情况:
- 混合锡化矿为高效太阳能电池提供可调节的带隙.
- 含锡的矿容易氧化,从而降低其光电子性能.
研究的目的:
- 为了研究氧气诱导的化物在混合锡化薄膜中.
- 了解氧气暴露对矿性能和长期稳定性的影响.
主要方法:
- 微波导电性测量
- 结构性表征
- 光学表征技术
主要成果:
- 氧气暴露会增加暗电导率,表明电子接受和锡氧化 (Sn2+到Sn4+),产生自由孔.
- 通过同时暴露在氧气和光线中,
- 观察到光导率降低和长期缺陷形成,即使在兴奋剂减少后.
- 长时间暴露会导致SnO2的形成和的损失,导致结构降解.
结论:
- 即使是短期的氧气暴露也会对矿的电荷载体动力产生负面影响.
- 随着长期暴露氧气和氧化产品的积累,结构性降解变得明显.
- 在生产和运行过程中严格排除氧气对于高效的-混合矿太阳能电池至关重要.
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