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Updated: Jun 8, 2025

A Continuous-flow Photocatalytic Reactor for the Precisely Controlled Deposition of Metallic Nanoparticles
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通过PdCu-TiO2光催化剂选择性氧化聚合物

Shuai Zhang1, Bernt Johannessen2, Bingquan Xia3

  • 1School of Chemical Engineering, The University of Adelaide, Adelaide, South Australia 5005, Australia.

Journal of the American Chemical Society
|November 6, 2024
PubMed
概括

这项研究提出了一种新的催化剂,用于利用光线将聚乙烯二甲 (PET) 塑料废物转化为有价值的化学物质. 先进的二氧化 (TiO2) 材料显著提高了塑料回收的效率和可持续性.

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The conversion of allylic alcohols into epoxides using the chiral catalyst was discovered by K. Barry Sharpless and is known as Sharpless epoxidation. The use of a chiral catalyst enables the formation of one enantiomer of the product in excess. This chiral catalyst is mainly a chiral complex of titanium tetraisopropoxide and tartrate ester (specific stereoisomer). The stereoisomer used in the chiral catalyst dictates the formation of the enantiomer of the product. In other words, the use of...
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