基于B/N的多共振框架的协同 π 扩展和外围锁定使高性能纯绿色有机发光二极管成为可能
Shengbing Xiao1,2, Xiaosong Cao1, Guohao Chen1
1Shenzhen Key Laboratory of New Information Display and Storage Materials, College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060, P. R. China.
Angewandte Chemie (International ed. in English)
|November 6, 2024
概括
新的多共振热激活延迟光 (MR-TADF) 发射器实现了高效率和颜色纯度的纯绿光. 这一突破提高了有机发光二极管 (OLED) 的性能和颜色范围.
科学领域:
- 有机电子学有机电子学
- 材料科学是一种材料科学.
- 光物理学的光学物理学
背景情况:
- 多共振热激活延迟光 (MR-TADF) 发射器是高效,广泛的OLED的关键.
- 目前的绿色MR-TADF发射器在颜色纯度和高效的反向系统间交叉 (RISC) 上扎.
研究的目的:
- 开发绿色MR-TADF发射器的协同分子设计.
- 为了克服OLED的颜色纯度和RISC效率的局限性.
主要方法:
- 采用了结合π延伸和外围锁定的分子设计.
- 合成和表征了四重玻里化MR-TADF发射器.
- 评估了设备性能,包括颜色坐标,量子产量和操作稳定性.
主要成果:
- 实现精确调整的纯绿色发射,其狭窄的FWHM为15nm.
- 证明了接近单位的量子产量和快速的RISC.
- 开发了CIE坐标 (0.18,0.74) 的无传感器OLED,接近BT.2020标准.
- 报告的最大外部量子效率 (EQE) 为36.6%和31.8%在1000cd/m2.
- 观察到设备寿命 (LT80) 在1000cd/m2.0下为485小时.
结论:
- 协同分子设计有效地提高了全面的OLED性能.
- 这一战略为开发高性能绿色OLED提供了一个有前途的途径.
- 开发的发射器显示了节能,广泛的颜色范围显示应用的潜力.
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