水友性和水性SiO2表面的环境下水浸透性
1Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, People's Republic of China.
The Journal of chemical physics
|November 8, 2024
概括
了解水 了解水 了解水
科学领域:
- 表面科学是一门学科.
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
背景情况:
- 二氧化 (SiO2) 表面的湿透性对于水相过渡至关重要,但在实验中仍在争论.
- 分子动力学 (MD) 模拟可以澄清复杂性,但在环境下温度的数据很少.
研究的目的:
- 通过使用MD模拟,研究SiO2表面的水接触角度在亚环境温度下.
- 探索基组分布,滴滴大小和基密度对湿度的影响.
主要方法:
- 在环境温度下对SiO2的水接触角度的实验测量.
- 在Q3,Q3/Q4和Q4SiO2表面的水接触角度的分子动力学 (MD) 模拟从220K到300K.
主要成果:
- 基密度显著影响SiO2表面湿透性和水接触角度.
- 较低的温度增加了水对Q3和Q3/Q4SiO2表面的亲和力.
- 温度下降降低了水前体膜的传播速度.
结论:
- 基密度是控制SiO2表面湿透性的主要因素.
- 较低的温度增加了水的亲和力,并改变了特定SiO2表面结构上的前体膜动态.
- 这项研究提供了对不同温度范围内的SiO2-水相互作用的见解.
相关概念视频
Cohesion
53.1K
Cohesion is the attraction between molecules of the same type, such as water molecules. Water molecules have an overall neutral charge but are polar molecule. An oxygen atom in one water molecule has a partial negative charge that can bind to a hydrogen atom with a partial positive charge in a second water molecule, forming a hydrogen bond. Each water molecule can form up to four hydrogen bonds with other water molecules. Hydrogen bonds are responsible for water's cohesive nature.
On a...
On a...
53.1K
Surface Tension, Capillary Action, and Viscosity
27.5K
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
27.5K
Solubility
17.3K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.3K


