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Updated: Jun 8, 2025

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
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Published on: October 3, 2014

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合成异体质 bis-phosphine bis-NHC 铁 (0) 综合体:增强小分子激活的战略

Christian M Andre1, Nathaniel K Szymczak1

  • 1Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, MI 48109, USA. nszym@umich.edu.

Chemical communications (Cambridge, England)
|November 8, 2024
PubMed
概括

研究人员使用bis-phosphine和bis-NHC连接体合成了新型的异体质铁复合体. 这些复合物表现出高度活化的铁(0) 状态,使其具有独特的反应性,如二的化.

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ortho–para-Directing Activators: –CH3, –OH, –⁠NH2, –OCH301:11

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