基表面活性剂的疏水性及其对抑制泡凝聚的作用
Rafael Del Río-Arrillaga1, Arturo A García-Figueroa1, José L López-Cervantes1
1Laboratorio de Superficies, Departamento de Fisicoquímica, Facultad de Química, Universidad Nacional Autónoma de México, Ciudad de México 04510, Mexico.
Molecules (Basel, Switzerland)
|November 9, 2024
概括
这项研究揭示了表面活性剂的疏水性和泡凝结之间的新的定量关系,引入了半凝结抑制度 (HCIC) 作为工业应用的关键预测参数.
科学领域:
- 合体和表面科学科学
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
背景情况:
- 泡凝聚对于发酵和废水处理等工业过程至关重要.
- 目前关于泡凝聚的研究主要集中在无机离子上,对有机离子和表面活性剂的数据有限.
- 表面活性剂广泛用于泡凝聚是一个重要的因素的行业.
研究的目的:
- 调查表面活性剂疏水性和气泡大小对气泡凝聚的影响.
- 解决关于有机离子和表面活性剂在泡凝聚研究中的数据缺口.
- 建立表面活性剂特性和凝聚行为之间的新型定量关系.
主要方法:
- 使用表面张力测量来量化表面活性剂的疏水性.
- 系统地分析了气泡大小和凝聚时间.
- 实验是在平面空气液体接口和气泡柱内进行的.
主要成果:
- 在表面活性剂的疏水性和半积抑制度 (HCIC) 之间发现了一种新的定量关系.
- 该研究发现,表面活性剂水性增加导致HCIC的增加.
- 这就建立了疏水性和HCIC之间的直接,比例关系,为凝聚控制提供了一个新的参数.
结论:
- 这些发现为预测和控制泡凝聚现象提供了一个新的参数 (HCIC).
- 这项研究增强了对多相系统中表面活性剂行为的理解.
- 建立的关系对于优化依赖泡动态的工业流程是有价值的.
相关概念视频
Entropy and Solvation
7.0K
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
7.0K
Solubility
17.3K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.3K
Colloids
17.4K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.4K
Electrophilic Aromatic Substitution: Sulfonation of Benzene
5.8K
Sulfonation of benzene is a reaction wherein benzene is treated with fuming sulfuric acid at room temperature to produce benzenesulfonic acid. Fuming sulfuric acid is a mixture of sulfur trioxide and concentrated sulfuric acid.
5.8K
Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility
43.9K
Intermolecular forces are attractive forces that exist between molecules. They dictate several bulk properties, such as melting points, boiling points, and solubilities (miscibilities) of substances. Molar mass, molecular shape, and polarity affect the strength of different intermolecular forces, which influence the magnitude of physical properties across a family of molecules.
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
43.9K
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation
4.3K
Unlike the easy catalytic hydrogenation of an alkene double bond, hydrogenation of a benzene double bond under similar reaction conditions does not take place easily. For example, in the reduction of stilbene, the benzene ring remains unaffected while the alkene bond gets reduced. Hydrogenation of an alkene double bond is exothermic and a favorable process. In contrast, to hydrogenate the first unsaturated bond of benzene, an energy input is needed; that is, the process is endothermic. This is...
4.3K


