"重新思考"硫治愈的方法
Anke Blume1, Frances van Elburg1, Fabian Grunert1
1Chair of Elastomer Technology & Engineering, Department of Mechanics of Solids, Surfaces & Systems (MS3), Faculty of Engineering Technology, University of Twente, 7522 NB Enschede, The Netherlands.
Molecules (Basel, Switzerland)
|November 9, 2024
概括
对于天然而言,已建立的硫固化机制可能不完全适用于现代轮胎跑道. 对于使用合成和填充剂的先进配方,重新考虑硫固化是必要的.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 技术 技术 技术
背景情况:
- 天然 (NR) 的硫化具有涉及氧化,酸,加速器和硫的成熟机制.
- 在NR中交叉连接主要发生在与双键相对的基位置上.
研究的目的:
- 研究传统的天然硫固化机制对现代轮胎跑道配方的适用性.
- 为了确定是否需要对合成与/系统混合物的硫固化进行重新评估.
主要方法:
- 对已确定的火山化机制的文献综述.
- 对现代轮胎胎面组成的分析,包括溶液丁 (SSBR) 和丁 (BR).
- 在合成化合物中考虑/填充系统.
主要成果:
- 广泛接受的天然火山化机制涉及到一个激活的加速器复合体.
- 现代乘用车轮胎使用合成 (SSBR/BR) 和/填充剂,与天然有很大不同.
结论:
- 将天然交叉连接知识直接转移到现代轮胎跑道上可能是不够的.
- "重新思考"硫固化可能是必要的,以优化当代轮胎配方的性能.
相关概念视频
Curing Methods
72
Concrete members with a small surface-to-volume ratio are cured by oiling and moistening the forms before casting the concrete member. These forms can be left in place for a prolonged period to prevent moisture loss, and can be wetted if made of a material suitable for wetting. If the forms are removed early, the concrete member is moistened and covered with polythene sheets to maintain moisture. For large horizontal concrete surfaces exposed to dry weather, a temporary covering is suspended...
72
Accelerated Curing of Concrete
113
Accelerating concrete curing is achieved by applying heat and additional moisture. This process accelerates the hydration of the cement, resulting in an earlier strength gain in the concrete. Steam curing is a method wherein the concrete products are either transported through a chamber on a conveyor belt or encased in plastic, allowing steam at atmospheric pressure to circulate freely around them. This process begins with a phase of moist curing that typically lasts between 3 to 5 hours, after...
113
Sulfur Assimilation
1
Sulfur is an essential element in biological systems, contributing to synthesizing key biomolecules, including amino acids such as cysteine and methionine, and cofactors such as coenzyme A and biotin. Microorganisms primarily assimilate sulfur as sulfate (SO₄²⁻) from the environment, which must undergo a series of biochemical transformations before it can be incorporated into cellular components. As sulfate is highly oxidized, it must undergo assimilatory sulfate reduction to...
1
Electrophilic Aromatic Substitution: Sulfonation of Benzene
5.8K
Sulfonation of benzene is a reaction wherein benzene is treated with fuming sulfuric acid at room temperature to produce benzenesulfonic acid. Fuming sulfuric acid is a mixture of sulfur trioxide and concentrated sulfuric acid.
5.8K
Preparation and Reactions of Sulfides
4.7K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
4.7K
Curing of Concrete
89
The hydration of cement takes place within the water-filled capillary pores. However, environmental elements can disrupt this process by evaporating water from the concrete surfaces. Sealed concrete with a water-cement ratio below 0.5 experiences self-desiccation, leading to water loss. The water loss in concrete is mitigated by curing. This technique involves keeping the concrete saturated to maintain the necessary temperature and moisture conditions, to optimally fill the spaces in the cement...
89


