评估饮用水处理残留物作为金属污染沉积物的现场封闭材料
Jingru Wei1, Yulin Zheng1, Lang Zhou1
1Department of Environmental Engineering Sciences, Engineering School of Sustainable Infrastructure and Environment, University of Florida, PO Box 116450, Gainesville, FL, 32611, USA.
Chemosphere
|November 9, 2024
概括
饮用水处理残留物 (DWTR) 有效地封闭了金属污染的沉积物,大大减少了金属释放和毒性. 包括吸附和沉在内的DWTR固定机制增强了沉积物修复工作.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 生态毒理学 生态毒理学
背景情况:
- 受金属污染的沉积物带来了生态风险.
- 现场封顶是污染沉积物的补救策略.
- 饮用水处理残留物 (DWTR) 是一种潜在的封闭材料.
研究的目的:
- 评估DWTR作为金属污染沉积物的现场封装材料.
- 评估DWTR在减少金属释放和毒性的有效性.
- 调查DWTR的金属固定机制.
主要方法:
- 胃腔实验测量金属在剪切应力下的释放.
- 96小时头小鱼 (FHM) 生物测试以评估金属毒性.
- 薄膜中的扩散梯度 (DGT) 用于分析金属配置文件和流量.
- ICP-MS用于金属度的确定.
主要成果:
- 限制DWTR显著降低了层水中的金属度 (例如,Cd从mg/L降低到μg/L范围).
- 封顶DWTR降低了金属毒性,防止了在非封顶和沙封顶沉积物中观察到的FHM死亡率.
- DGT显示,DWTR在沉积物-水界面的金属流量减少了多达两倍.
结论:
- DWTR是一种有效的现场封装材料,用于金属污染沉积物.
- 在物理屏障效应之外,DWTR通过吸附和沉来固定金属.
- DWTR显著降低了金属毒性和受污染沉积物的生态风险.
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