使用γ-MnO从地热盐中提取:图兹拉地热发电厂的一个案例研究
Seyra Toprak1, Çınar Öncel2, Sinan Yılmaz3
1Department of Materials Science and Engineering, İzmir Institute of Technology, 35430, Gülbahçe, Urla, İzmir, Turkey.
Heliyon
|November 11, 2024
概括
电解二氧化 (γ-MnO2) 有效地从地热盐水中提取离子. 这种吸附剂显示出从自然来源可持续回收的承诺,即使在多次使用后也是如此.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 地质化学 地质化学
背景情况:
- 地热盐水中含有丰富的有价值元素,为资源回收提供了机会.
- 从地热盐水等复杂的自然系统中提取元素是具有挑战性的.
- 以前的实验室规模研究可能不准确地反映现实世界的表现.
研究的目的:
- 研究电解二氧化 (γ-MnO2) 作为从地热盐中提取的吸附剂的使用.
- 在现场条件下评估γ-MnO2的吸附和脱附性能.
- 评估γ-MnO2吸附剂的可重复使用性和效率.
主要方法:
- 一个小型试验反应堆部署在土耳其图兹拉地热发电厂 (TGPP) 的再注入井中.
- 电解性γ-MnO2被用作离子 (Li+) 吸附的吸收材料.
- 吸附在360K和2巴进行,在酸性溶液中进行脱吸.
主要成果:
- 在TGPP下,在1小时内达到最大的吸附性能.
- 在30毫升酸性溶液中使用10克γ-MnO2的溶液中,溶解后的平均Li+度为25mg/L.
- 在连续四次循环后,累积脱吸达到230 mg/L Li+.
- 在多次使用后,γ-MnO2吸附剂保留了大约40%的初始性能.
结论:
- 电解式γ-MnO2是一种有前途且具有成本效益的吸附剂,用于从地热盐水中提取.
- 开发的吸附/脱附过程证明了从自然,复杂的水系统中回收的实际潜力.
- 吸附剂的可重复使用性表明工业应用的经济可行性.
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