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Updated: Jun 7, 2025

Demonstrating the Simplicity and In Situ Temperature Monitoring of the Mechanochemical Synthesis of Metal Chalcogenides Suitable for Thermoelectrics
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Demonstrating the Simplicity and In Situ Temperature Monitoring of the Mechanochemical Synthesis of Metal Chalcogenides Suitable for Thermoelectrics

Published on: August 30, 2024

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在分子连接处自组装的本佐提-本佐提单层的热电特性

Sergio Gonzalez-Casal1, Rémy Jouclas2, Imane Arbouch3

  • 1Institute for Electronics Microelectronics and Nanotechnology (IEMN), CNRS, Av. Poincaré, Villeneuve d'Ascq 59652, France.

The journal of physical chemistry letters
|November 11, 2024
PubMed
概括

我们研究了二-二 (BTBT) 分子结的热电特性. C8-BTBT-C8中的链降低了导热,而弱合提高了Seebeck系数,产生了高达10^-4.4的功率 (ZT).

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Structure of Benzene: Molecular Orbital Model

According to the molecular orbital (MO) model, benzene has a planar structure with a regular hexagon of six sp2 hybridized carbons. As shown in Figure 1, each carbon is bonded to three other atoms with C–C–C and H–C–C bond angles of 120°. The C–H bond length is 109 pm, and the C–C bond length is 139 pm which is midway between the single bond length of sp3 hybridized carbons (154 pm) and sp2 hybridized carbons (133 pm).
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The simplest conjugated diene is 1,3-butadiene: a four-carbon system where each carbon is sp2-hybridized and has an unhybridized p orbital that contains an unpaired electron. According to molecular orbital theory, atomic orbitals combine to form molecular orbitals such that the number...
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