能量波段对齐和缺陷协同调节使空气溶液处理的石太阳能电池具有最低的VOC缺口
Yunhai Zhao1,2, Xingye Chen1, Shuo Chen1
1Institute of Thin Film Physics and Applications, Shenzhen Key Laboratory of Advanced Thin Films and Applications, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, State Key Laboratory of Radio Frequency Heterogeneous Integration, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, 518060, China.
在铜锡硫化 (CZTSSe) 太阳能电池中用Ag和In替代双离子,可显著降低电压损失并提高效率. 这一策略增强了带线对齐和使缺陷无效,从而提高了光伏设备的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 半导体物理 半导体物理
背景情况:
- 高性能铜锡硫化 (CZTSSe) 太阳能电池面临开放电路电压缺陷 (VOC-def) 的挑战.
- 不良的接口带对齐和高密度散装缺陷有助于载体重组和降低设备效率.
研究的目的:
- 为了解决CZTSSe太阳能电池中的VOC赤字.
- 改进接口带对齐,并通过协同子替代减少有害的散装缺陷.
主要方法:
- 在CZTSSe中对Ag和In双的协同替代.
- 通过In-S/Se和Sn-S/Se键进行带对齐调节的分析.
- 抑制Cu─Zn障碍和通过Ag,In替代Sn相关缺陷的被动化.
- 评估载体特性和设备性能.
主要成果:
- 实现了14.33%的高效空气溶液处理的CZTSSe太阳能电池,具有580mV VOC.
- 在 CZTSSe 字段中获得了最低的 VOC-def (64.7% 的 VOCSQ).
- 证明增强载体寿命和少数载体扩散长度.
- 成功调节了带对齐,缺陷级别和载体传输.
结论:
- 协同的Ag和In双离子替代是一种高性能CZTSSe太阳能电池的有效策略.
- 这种方法同时改善了带线对齐,减少了缺陷,并增强了载体特性.
- 为开发先进的光伏设备铺平了一条方便的道路.
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