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Updated: Jun 7, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

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通过分子工程促进水激活,在CO2电还原过程中实现有效的非对称C-C合

Zi-Yu Du1, Si-Bo Li1, Ge-Hao Liang1

  • 1State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, College of Materials, iChEM, Fujian Key Laboratory of Advanced Materials, College of Energy, Institute of Artificial Intelligence, Xiamen University, Xiamen 361005, China.

Journal of the American Chemical Society
|November 13, 2024
PubMed
概括

使用富含N-H分子的工程铜表面增强了电化学二氧化碳的减少,使其成为有价值的C2产品,如乙烯和乙醇. 这一战略加快了水的激活,并提高了可持续化学生产的催化效率.

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Overview
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Thermal Electrocyclic Reactions: Stereochemistry

The stereochemistry of electrocyclic reactions is strongly influenced by the orbital symmetry of the polyene HOMO. Under thermal conditions, the reaction proceeds via the ground-state HOMO.
Selection Rules: Thermal Activation
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