在广泛的pH范围内,一种新的三元性疏水型深溶剂用于回收
Jinglin Chen1, Zhong Tian2, Guisu Yu3
1School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, PR China.
Journal of hazardous materials
|November 13, 2024
概括
一种新型的疏水性深度浸泡溶剂 (HDES) 能有效地从水溶液中回收 (Li). 这种绿色技术在广泛的pH范围内提供了高选择性和稳定性,促进了可持续的提取.
科学领域:
- 材料科学 材料科学 材料科学
- 绿色化学 绿色化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 全球对 (Li) 的需求不断增长,因为它在绿色技术和能源存储方面发挥着至关重要的作用.
- 需要有效和选择性的从水溶液中回收的方法.
- 现有的提取方法的局限性,通常需要恶劣的性条件.
研究的目的:
- 开发和评估一种新型的三元性疏水型深溶剂 (HDES),用于有效的回收.
- 为了研究HDES在广泛的pH范围内的性能.
- 阐明HDES选择性提取的机制.
主要方法:
- 一种新型三元HDE的合成,其中包括2-thiophenyltrifluoroacetone (HTTA),trioctylphosphine氧化物 (TOPO) 和N,N-diethyldecanamide (DDA).
- 系统评估提取效率作为初始水性pH的函数.
- 动力学研究以确定提取平衡时间.
- 福里埃变换红外光谱法 (FT-FTIR) 用于确认Li (I) 和HDES组件之间的相互作用.
- 使用工业Li2CO3母液进行反流提取实验.
主要成果:
- 开发的HDES证明了从水溶液中提取Li的高效率和选择性.
- 稳定的HDES性能在pH范围3-13中被观察到,比传统方法提供了更广泛的应用窗口.
- 实现了快速提取动力学,在10分钟内达到平衡,没有乳化.
- 在TOPO和DDA的支持下,Li (I) 和TTA之间的静电相互作用被确定为选择性提取的主要机制.
- 反流提取实现了98.704%的回收率和10643.14.4.1的 (I) / (I) 分离因子.
结论:
- 三元的HDES为回收提供了一个高效,选择性和环保的替代方案.
- 它在广泛的pH范围内的稳定性能提高了它在工业环境中的适用性.
- 证明的高提取和分离效率突出显示了该HDES在可持续资源管理方面的巨大潜力.
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