含有改性粉的聚合物树脂作为染料的环保吸附剂,并从废水中去除金属离子
Anna Wołowicz1, Monika Wawrzkiewicz1, Beata Podkościelna2
1Faculty of Chemistry, Institute of Chemical Sciences, Department of Inorganic Chemistry, Maria Curie-Sklodowska University in Lublin, Lublin, Poland.
Frontiers in chemistry
|November 14, 2024
概括
新的聚合物微球有效地从水中去除染料和重金属. 改性粉提高了热稳定性和吸附能力,为废水处理提供了可持续的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 聚合物科学 聚合物科学
背景情况:
- 吸附是清除水中的杂质的关键.
- 需要具有成本效益,高效和环保的吸附剂.
- 自然的,可再生的来源是首选的吸附剂制备.
研究的目的:
- 开发新的聚合物微球吸附剂.
- 使用改性粉来增强其性能.
- 评估从水中去除染料和重金属的情况.
主要方法:
- 合成的乙烯基醇二甲基酸盐 (EGDMA) 和乙烯酸乙烯 (VA) 微球.
- 含有酸 (B) 或二甲-S-氨酸二甲酸 (DiTDTA) 改性粉.
- 使用ATR/FT-IR,DSC,SEM,BET,EDS和pHpzc的特征吸附剂.
主要成果:
- 改性粉增加了热电阻和改变了表面电荷 (pHpzc).
- 微球表现出具有显著表面积的中孔结构.
- 对于C.I.来说,它具有很高的吸附能力. 基本蓝色3 (BB3) 染料 (高达194毫克/克) 和重金属 (Cu,Ni,Zn).
- 在20-120分钟内达到快速吸附平衡.
结论:
- 有改性粉的EGDMA/VA微球是有效的吸附剂.
- 吸附性能受到接触时间,度和溶液化学的影响.
- 弗洛伊德利希等温模型最好地描述了吸附平衡数据.
- 使用甲醇/HCl或HCl溶液实现了高效的脱吸.
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