在水/蒸汽界面上被吸附的表面活性剂诱导的同位素异位素表面几何转换
Nitesh Kumar1, Joshua Bilsky1, Aurora E Clark1
1Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, USA.
The Journal of chemical physics
|November 14, 2024
概括
表面活性剂的吸附会改变水面的几何形状,从同位素曲率过渡到异位素曲率. 较小的表面活性剂可以诱导异性向异性转变,稳定表面波.
科学领域:
- 物理化学 物理化学
- 表面科学是一门学科.
- 材料科学 材料科学 材料科学
背景情况:
- 接口上的吸附剂改变了表面张力和几何形状.
- 对表面几何变化的详细理论研究是有限的.
- 应用往往依赖于整体平均表面特征.
研究的目的:
- 为了研究表面活性剂吸附如何影响水/蒸汽接口几何.
- 分析不同表面活性剂度和硬度的表面曲率和方向分布.
- 根据表面活性剂的特性来识别表面几何中的过渡.
主要方法:
- 表面曲率和方向分布的理论分析.
- 在水/蒸汽界面检查微酸 (TBP) 吸附的情况.
- 表面几何变化与不同基酸盐表面活性剂尾部长度的比较.
主要成果:
- 在低酸 (TBP) 密度下,出现具有相反标志和相似大小的主要曲率的脊柱.
- 增加TBP密度会导致更明显的脊和异性质的表面曲率 (异性质→异性质过渡).
- 较小的基酸盐表面活性剂会诱导一种异型→异型过渡,稳定和对称表面波.
结论:
- 表面几何学高度依赖于表面活性剂度和分子结构.
- 观察到不同的几何过渡 (同位素-异位素和异位素-同位素).
- 这些发现为像毛细管波理论这样的统计理论提供了更现实的表面几何分布.
更多相关视频
相关概念视频
Surface Tension, Capillary Action, and Viscosity
27.5K
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
27.5K
Surface Tension of Fluid
241
Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies...
Surface tension varies...
241
Surface Tension and Surface Energy
1.3K
When a paint brush is immersed in water, the bristles wave freely inside the water. When it is taken out, the bristles stick together. The reason behind this effect is surface tension.
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
1.3K
Entropy and Solvation
7.0K
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
7.0K
Intermolecular Forces and Physical Properties
20.4K
20.4K
Contact Angle
11.8K
When a solid is dipped inside a liquid, the liquid surface becomes curved near the contact. For some solid–liquid interfaces, the liquid is pulled up along the solid, while for others, the liquid surface is convex or depressed near the solid surface. This phenomenon can be explained using the concept of cohesive and adhesive forces.
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
11.8K


