冷-解周期的事件使生物炭的深层分解成为可能:释放溶解的黑碳及其结构依赖的碳封存能力
Lang Zhu1, Na Chen1,2, Xianglei Zhang1
1College of Natural Resources and Environment, Northwest A & F University, Yangling 712100, China.
Environmental science & technology
|November 14, 2024
概括
结解周期显著增加生物炭中溶解的黑碳 (DBC) 的释放,降低了土壤的保留能力. 这会影响寒冷地区的碳储存.
科学领域:
- 环境科学 环境科学
- 土壤科学 土壤科学
- 碳循环是碳循环的过程.
背景情况:
- 生物炭被认为是一种稳定的土壤碳池.
- 冰解周期对生物炭溶解黑碳 (DBC) 释放和土壤保留的影响还未得到充分研究.
研究的目的:
- 在冷解周期下,研究DBC从生物炭中释放的DBC.
- 评估这些循环对生物炭土壤保留能力的影响.
- 描述释放的DBC的特性.
主要方法:
- 在300-700°C的生物炭的热解.
- 对生物炭的冷解周期的应用.
- 量化DBC释放的数量 (mg C L-1).
- 测量DBC土壤保留能力.
- 使用SEC,FEEM,FTIR和NMR对DBC组成进行分析.
主要成果:
- 结解周期增加了DBC释放的数量 (33.08230.74毫克C L-1).
- DBC释放动力学因生物炭热解温度而有所不同.
- 在土壤中结解引起的DBC的保留率下降了7.729.5%.
- 在冷解DBC中增加的水友性低分子量化合物有助于减少保留.
结论:
- 结解周期增强DBC的释放并减少其在土壤中的保留.
- DBC中的水友化合物促进水相度,增加碳外流.
- 这些发现凸显了生物炭碳池在寒冷环境中的脆弱性.
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