合成,性能评估和吸附-分散机制的硫酸终结的长侧链聚碳酸超可塑化剂
Haotian Duan1, Tianfeng Zhou1, Beibei Li1
1School of Chemistry and Chemical Engineering, Guangdong Provincial Key Lab of Green Chemical Product Technology, State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.
Langmuir : the ACS journal of surfaces and colloids
|November 14, 2024
概括
引入硫酸终结聚碳酸盐 (PCEPS) 提高了混凝土添加剂的性能. 这些PCEPS通过减少结构崩来增强分散性和稳定性,比传统的超级增塑剂提供更高的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 聚合物化学 聚合物化学
背景情况:
- 聚碳酸超可塑剂 (PCE) 对于混凝土的可加工性至关重要.
- 在PCE中长的聚乙烯侧链可能导致结构崩,限制其有效性.
- 开发新的PCE结构对于提高混凝土添加剂性能至关重要.
研究的目的:
- 合成和评估硫酸终结聚碳酸盐 (PCEPS) 作为先进的混凝土添加剂.
- 调查硫酸终结对PCE分散和水泥系统稳定性的影响.
- 为了比较PCEPS与常规的碳素终结PCE的性能.
主要方法:
- 硫酸终结聚碳酸盐 (PCEPS) 的合成.
- 使用圆测等技术,对吸附层厚度 (ALT) 的表征.
- 在水泥混合物中评估分散,粘土耐受性和沉保留.
- 与传统的聚碳酸乙烯 (PCEC) 和碳酸终结的长侧链聚碳酸 (PCETA) 进行比较.
主要成果:
- 与传统的PCE相比,PCEPS在水泥中显著增强了分散.
- PCEPS-4000的吸附层厚度 (11.65 nm) 比PCETA (7.93 nm) 更大.
- 引入硫酸组减少了结构崩,并改善了侧链延伸.
结论:
- 硫酸终结有效地减轻PCE的结构崩,从而改善分散.
- PCEPS提供卓越的性能,包括增强的分散性,粘土耐受性和沉保留性.
- PCEPS代表了一种多功能和有效的下一代混凝土添加剂.
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