热调节的花 - 凝结过程通过温度响应的阴离子聚合物表面活性剂,用于增强的原油-水分离
Xianwu Zhang1, Yijun Cao2, Dan Yang1
1School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China.
Journal of hazardous materials
|November 16, 2024
概括
温度敏感的聚合物表面活性剂 (Q-g-PN) 通过控制花和凝结来增强油水分离. 这些新型表面活性剂根据温度调整它们的结构,提高了脱过程的效率.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 合体和表面化学
背景情况:
- 聚合物表面活性剂对于花辅助凝聚至关重要,但它们的大分子可以阻碍油滴凝聚.
- 聚合物表面活性剂的固体阻碍阻碍了乳液中高效的油水分离.
研究的目的:
- 设计和合成温度敏感的聚合物表面活性剂 (四级基-g-PNIPAM,Q-g-PN) 以提高油水分离.
- 研究热调节的花凝聚机制,以提高脱效率.
主要方法:
- 合成Q-g-PN通过将热响应部分集成到cationic chitosan上.
- 通过在不同温度下进行瓶式试验,评估油水分离效率.
- 分子动力学 (MD) 模拟研究Q-g-PN行为和油滴相互作用.
主要成果:
- Q-g-PN证明了可调节的结构变化与温度,在水友性延伸和疏水性线圈状态之间过渡.
- 通过温度调节,在0.001%的低Q-g-PN度下达到高达94%的脱硫效率.
- 通过实验和模拟数据证实了热调节的花和凝聚的机制.
结论:
- 对温度敏感的聚合物表面活性剂为高效的油水分离提供了一种新的策略.
- 通过温度控制精确调节分子相互作用,增强了花-凝结过程.
- 在各种工业应用中,Q-g-PN为改善脱硫提供了一个有希望的解决方案.
相关概念视频
Colloids
17.4K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.4K
Coagulation
273
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
273
Colloidal precipitates
517
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
517


