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素激素激活矿基质埋藏的异质接口,以实现无孔运输层的锡基太阳能电池,其效率超过14%

Gengling Liu¹, Xianyuan Jiang², Yaorong He¹

¹Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, LIFM, School of Chemistry, IGCME, Sun Yat-sen University, Guangzhou, 510275, P. R. China.

Angewandte Chemie (International ed. in English)

|November 18, 2024

概括

这项研究介绍了一种基桥梁方法,以创建高效,稳定和低成本的基矿石太阳能电池,没有孔运输层. 这一创新简化了设备结构,提高了性能.

科学领域:

材料科学材料科学材料科学
可再生能源可再生能源是可再生能源.
太阳能光伏发电是如何实现的

背景情况:

基矿是有希望的环保太阳能材料,但在成本效益高的生产和运营稳定性方面面临挑战.
现有的基于的矿太阳能电池 (PSC) 受到昂贵的孔运输材料 (HTM) 和低于最佳的接口的阻碍.

研究的目的:

开发一种新的战略,用于制造高性能,简化的基于Sn的PSC.
通过优化氧化物 (ITO) /矿接口,消除了对HTM的需求.

主要方法:

使用基化学桥梁 (Cl-RCB) 策略来修改 ITO 电极.
这种方法减轻了氧气空缺,改变了化学成分,并调整了ITO的工作功能.
该战略优化了ITO/矿异质接口,减少了能源障碍,改善了载体动态.

主要成果:

无HTL的基于Sn的PSC实现了14.20%的创纪录效率,相当于含有HTL的设备.
Cl-RCB策略显著降低了0.20 eV的界面能量屏障.
优化的设备表现出增强的稳定性,运行长达2000小时.
该方法成功地应用于基于Pb和混合Sn-Pb的PSC,效率分别为22.27%和21.13%.

结论:

临床-RCB战略为生产高效和稳定的无HTLPSC提供了可行的途径.
这种方法简化了设备架构,降低了生产成本.
Cl-RCB的多功能性延伸到各种矿组成,推进了简化太阳能电池领域.

关键词:

基于的矿石.没有无孔运输层的孔.接口载体动态的载体动态.激进化学化学激进化学太阳能电池是太阳能电池中的一个.

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