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联体效应诱导的电子结构操纵介质合金的介质合金,在减少氧气的5万个循环中获得了非凡的稳定性

Sijie Chen1, Dingwen Bao1, Luping Zhang1

  • 1School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China.

Inorganic chemistry
|November 19, 2024
PubMed
概括

新的PdRhNi合金网络为离子交换膜燃料电池 (AEMFC) 提供了增强的耐用性和活性. 这一进步解决了非贵金属溶解的问题,提高了氧降解反应 (ORR) 的效率,并为商业化铺平了道路.

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In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
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