在危险废物中准重金属的固定相,以轻质聚合物为基础的轻质聚合物
Baodong Li1, Shouwei Jian2, Xin Gao2
1School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China; Department of Architecture and Civil Engineering, Chalmers University of Technology, Gothenburg 412 96, Sweden.
Journal of hazardous materials
|November 20, 2024
概括
当Pb,Cu,Cr和Ni等重金属被固定时,将危险废物回收成轻质聚合物 (LWA) 更安全. 这项研究发现,特定的矿物阶段有效地结合这些金属,减少回收材料中的漏风险.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 地质化学 地质化学
背景情况:
- 将危险废物大规模回收成轻质聚合物 (LWA) 面临挑战,因为可能会有重金属的漏.
- 有效的固定化策略对于安全利用这些回收材料至关重要.
研究的目的:
- 研究从危险废物中获得的LWA中重金属 (Pb,Cu,Cr,Ni) 的固定机制.
- 评估特定矿物阶段 (地,螺旋) 在减少重金属漏中的作用.
主要方法:
- 使用理论计算和实验验证来确定重金属组合状态.
- 在高温下分析重金属与地和旋相相互作用的分析.
主要成果:
- (Pb) 在地晶体结构中形成稳定的间歇性固体溶液.
- 铜 (Cu), (Cr) 和 (Ni) 在旋转阶段形成替代固体溶液.
- 虽然物理性能略有降低,但添加固定阶段显著降低了漏风险.
- 阿尔比特在玻璃状阶段促进了Pb的固定,而由于粘度更高,阿诺石的有效性较低.
结论:
- 特定的矿物阶段,即地和螺旋,可以有效地固定基于危险废物的重金属LWA.
- 控制固定相的添加提供了一个可行的策略,以减轻重金属漏,并提高回收材料的安全性.
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