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Research and Development of High-performance Explosives
Published on: February 20, 2016
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关于TNTON/DNTF高温特征的研究:基于低高温混合物的造爆炸物载体的探索
Xinyu Feng1, Qi Xue1, Junlin Zhang1,2
1Xi'an Modern Chemistry Research Institute Xi'an 710065 China bifuqiang@msn.com wbz600@163.com.
RSC advances
|November 21, 2024
概括
为了改进DNTF,开发了一种由3,5,5-trinitro-1,3-oxazinane (TNTON) 和DNTF组成的新型优化系统.
科学领域:
- 能量材料科学 能量材料科学
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
背景情况:
- DNTF (1,1-diamino-2,2-bis(nitramino) -4,4,5,5-tetranitrobicyclohexa-1,5-diene) 是一种高能爆炸物.它是一种高能爆炸物.
- 修改DNTF的灵敏度和点对于其安全处理和应用至关重要.
- 欧特克系统提供了一种有希望的方法来调整爆炸性质.
研究的目的:
- 准备一种由3,5,5-trinitro-1,3-oxazinane (TNTON) 和DNTF.构成的新型体系统.
- 为了研究TNTON/DNTF的融化行为,热稳定性和敏感性.
- 为了评估新型的Eutectic爆炸组合的爆炸性能.
主要方法:
- 在不同比例下制备TNTON/DNTF欧特混合物.
- 不同扫描热量计 (DSC) 和热重力计分析 (TGA) 测量热行为.
- 冲击和摩擦敏感性测试.
- 使用EXPLO-5软件计算爆炸性能.
主要成果:
- 测定TNTON/DNTF欧特克的固体构成为58.26:41.74,点为69°C.
- 体表现出随着加热速度的增加而延迟的化和分解,这表明它具有良好的热稳定性.
- 与单独使用DNTF相比,冲击灵敏度 (38J) 和摩擦灵敏度 (252N) 显著降低.
- 计算的爆炸速度达到了8921 m s−1 ,理论密度为1.906 g cm−3.
结论:
- 在TNTON/DNTF的Eutectic系统有效地降低了DNTF的灵敏度,同时保持高能量输出.
- 与TNT爆炸剂相比,这种优质的组合显示出更高的爆炸性能.
- 研发的超性爆炸物对需要高能量的平衡和改进的安全特性的应用具有前景.
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