向可持续性充电:MgCl2化奇托-德克斯多混合电解质用于储能设备应用
Pradeep Nayak1, Ismayil1, Y N Sudhakar2
1Department of Physics, Manipal Institute of Technology, Manipal Academy of Higher Education Manipal 576104 Karnataka India ismayil.mit@manipal.edu ismayil.486@gmail.com +91 98454 97546.
RSC advances
|November 21, 2024
概括
这项研究开发了一种可生物降解的固体混合聚合物电解质 (SBPE) 来自奇托,德克斯和化. 优化的SBPE显示出对离子电池和电化学双层电容器有望的离子导电性和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 聚合物科学 聚合物科学
背景情况:
- 开发固态电解质对于更安全,更高效的储能设备至关重要.
- 离子电池比离子电池具有潜在的优势,但需要合适的电解质.
- 寻求可生物降解和具有成本效益的材料用于可持续能源技术.
研究的目的:
- 为了合成和表征一种基于奇托 (CS),德克斯 (DN) 和化 (MgCl2) 的新型固体混合聚合物电解质 (SBPE),用于Mg2+离子导电.
- 评估开发的SBPE的电化学特性,包括离子导电性,离子转移数和电化学稳定性窗口 (ESW).
- 研究SBPE在离子电池和电化学双层电容器 (EDLC) 的性能.
主要方法:
- 通过将MgCl2盐加入CS-DN聚合物混合物中,合成SBPE膜.
- 使用X射线衍射 (XRD) 和富里埃变换红外光谱 (FTIR) 的微结构分析.
- 电化学表征包括离子导电量测量,离子转移数 (t ion) 确定,电化学稳定窗口 (ESW) 评估和循环电压计 (CV) 用于EDLC性能.
主要成果:
- XRD和FTIR证实了成功的多混合离子相互作用和MgCl2合并后的结构变化.
- 使用30%重量%的MgCl2的SBPE膜在室温下表现出1.79 × 10^-5 S cm^-1的离子导电性.
- 实现了0.73的离子转移数和2.66V的ESW,这表明占主导地位的离子导电和良好的稳定性.
- 制造出来的EDLC在5mVs-1时显示了36Fg-1的特定电容.
结论:
- 开发的CS + DN + MgCl2 SBPE是一种有前途的可生物降解和具有成本效益的电解质材料.
- 在储能应用中,SBPE表现出有利的离子导电性,离子运输优势和电化学稳定性.
- 该材料显示了作为离子电池和EDLC中的分离器和电解质的使用潜力.
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