介电电容器的自我修复:一种通用方法来计算新引入的储能设计的计算率
Nadezhda A Andreeva1, Vitaly V Chaban2
1Peter the Great St. Petersburg Polytechnic University, Saint Petersburg, Russia. andreeva_na@spbstu.ru.
Physical chemistry chemical physics : PCCP
|November 21, 2024
概括
研究人员开发了一种通用方法来预测电容器故障产品. 聚烯 (PP) 电容器产生更多的气体和不太导电的烟尘,而卡普顿电容器产生更少的气体和更导电的烟尘,有助于性能预测.
科学领域:
- 材料科学 材料科学 材料科学
- 电气工程 电气工程
- 计算化学计算化学
背景情况:
- 金属膜电容器的介电分解,由微放电引起,形成导电性烟尘通道,降低性能并导致故障.
- 聚合物介电材料提供更均的层,但不能完全防止微放电和随后的烟尘形成.
研究的目的:
- 开发一种通用计算方法,用于预测金属化薄膜电容器中介电分解产物的组成和特性.
- 评估和比较基于聚烯 (PP),聚乙烯二甲 (PET),聚碳酸 (PC) 和卡普顿的电容器的分解特性.
主要方法:
- 利用电子结构模拟和潜在的景观探索来预测分解产品的特性.
- 分析了由不同介电材料 (PP,PET,PC,Kapton) 形成的烟尘的气态产品产量和电导率.
主要成果:
- 聚烯 (PP) 产生了最多的气体产品 (12.3%重量%) 与最低的烟尘导电性.
- 卡普顿展示了最少的气态产品 (5.1 wt%),但是最高的烟尘导电性.
- 苏特电导率排名:PP < PET < PC < 卡普顿.
- 排名中的气态产品含量:PP (12.3%重量%) >PC (6.4%重量%) >PET (6.2%重量%) >卡普顿 (5.1%重量%).
结论:
- 开发的计算方法准确地预测了电容器分解产品的性能和性能.
- 结果与自我愈合效率的实验数据一致,验证了电容器设计的预测能力.
- 这种方法使许多假设电容设计的快速计算选成为可能,加速了工程进步.
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