辐射能量转移使上转换循环偏振持久发光用于多层次信息加密
Haolai Mao1,2, Xuefeng Yang2, Yonghong Shi2
1Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, P. R. China.
Nanoscale
|November 22, 2024
概括
研究人员开发了先进的向上转换的循环极化持久发光 (UC-CPPL) 材料,以加强防伪. 这种新型材料将上转换纳米粒子和光体集成到奇拉性阴性液晶中,以实现安全,多层次的信息加密.
科学领域:
- 材料科学 材料科学 材料科学
- 光电学是指光电子产品.
- 光子学是指光子学的使用方法.
背景情况:
- 光学活性持久发光材料为防伪提供独特的极化特性.
- 开发向上转换的循环极化持久发光 (UC-CPPL) 材料带来了重大的制造挑战.
- 现有的材料缺乏用于先进信息加密的集成功能.
研究的目的:
- 为构建UC-CPPL材料提出一个有效的策略.
- 通过奇拉性阴性液晶实现放大循环极化持久发光.
- 通过集成光学特性实现复杂和安全的信息加密.
主要方法:
- 嵌入上转化纳米粒子 (UCNPs) 和体到性阴性液晶 (N*LC).
- 在近红外激发时,利用UCNP和之间的辐射能量传递机制.
- 调整性N*LC的光子带隙,以放大发光不对称性.
主要成果:
- 在N*LC中,通过UCNP和酸成功制造了UC-CPPL材料.
- 实现了放大UC-CPPL发光不对称系数 (g_UC-CPPL) 到大约0.6.6.
- 证明了循环极化发光,持久发光和向上转换发光的集成.
结论:
- 开发的UC-CPPL材料为先进的防伪应用提供了一个有前途的平台.
- 多个光学属性的集成使复杂和安全的信息加密成为可能.
- 这种方法有助于控制隐藏和选择性释放加密信息,并增强安全性.
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