通过石墨-亚摩尔结构的协同工程实现了刚性-灵活的合,用于持久和快速的储存
Mingchi Jiang1, Ning Sun1, Bin Cao2
1State Key Laboratory of Organic-Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing, 100029, China.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|November 22, 2024
概括
工程部分石墨碳通过提高阳极循环性能来增强离子电池 (PIB). 这种新的碳结构为先进的储能解决方案提供了高容量和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 石墨阳极在离子电池 (PIB) 中表现有前途.
- 由于层间膨胀导致的循环性能差,限制了实际的 PIB 应用.
- 开发稳定和高性能阳极对于GDPs至关重要.
研究的目的:
- 为了改进部分石墨碳 (PGC) 阳极以提高离子电池的性能.
- 为了研究碳结构和离子储存之间的关系.
- 提高 PIB 的循环稳定性和能量密度.
主要方法:
- 使用铁酸盐和的催化合成PGC.
- 系统地改变催化剂含量以优化碳结构.
- 电化学特性 (容量,循环稳定性,速率能力).
- 在现场XRD和DFT模拟以阐明机制.
主要成果:
- 优化的PGC12电极实现了281.9 mAh的g-1可逆容量.
- 卓越的循环稳定性,在300个循环后保持94.8%.
- 令人印象深刻的速率能力 (222.2 mAh g-1 在 1 C) 和高能量密度 (148.2 Wh kg-1).
结论:
- 工程PGC结构平衡了石墨和无形区域,以实现高效的K离子存储.
- 优化的阳极设计显著提高了PIBs的循环性能和能量密度.
- 这项工作为离子电池的先进碳阳极的合理设计提供了见解.
相关概念视频
Network Covalent Solids
13.4K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
13.4K
Alkali Metals
19.1K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
19.1K
Ionic Crystal Structures
14.1K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.1K
Molecular and Ionic Solids
16.9K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
16.9K
MOS Capacitor
707
A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
707
Crystal Field Theory - Octahedral Complexes
26.2K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
26.2K


