SnOx表面改性Sr2Fe1.5Mo0.5O6-δ阴极具有增强的电催化活动,用于直接CO2电解在固体氧化物电解细胞中
Enli Wang1, Liang Zhao2, Zhibin Yang3
1College of Energy, Soochow Institute for Energy and Materials Innovations, Soochow University, Suzhou 215006, China; Research Center of Solid Oxide Fuel Cell, China University of Mining and Technology-Beijing, Beijing 100083, China.
Journal of colloid and interface science
|November 23, 2024
概括
用SnOx纳米颗粒对矿氧化物阴极进行表面修饰,可以提高固体氧化物电解细胞 (SOEC) 中的CO2减小反应 (CO2RR) 动力学. 这提高了高效的CO2电解的性能和耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 催化剂是一种催化剂.
背景情况:
- 在SOEC中CO2RR的缓慢动力学限制了效率.
- 矿氧化物阴极是有希望的,但需要优化.
- 表面修改是提高阴极性能的一个关键策略.
研究的目的:
- 为了加速SOEC中的CO2RR动力学.
- 为了提高矿氧化物阴极的性能和耐用性.
- 调查SnOx纳米粒子表面修饰对SFM阴极的影响.
主要方法:
- 简单的湿浸透方法,将SnOx纳米颗粒加载到Sr2Fe1.5Mo0.5O6-δ (SFM) 阴极上.
- 修改后的SFM@SnOx 阴极的特性.
- 用SFM@SnOx阴极进行CO2电解的SOEC的性能评估.
主要成果:
- SFM@SnOx阴极表现出增强的特定表面积和三相边界.
- 观察到优化的CO2吸附/激活和额外的氧气空缺.
- 在1.5V和850°C时达到0.691 A cm-2的高电流密度.
- 在1.2V和800°C下经过100小时的稳定运行,没有衰减.
结论:
- 用SnOx纳米颗粒修改SFM阴极的表面对CO2RR有效.
- 在SOEC中,SFM@SnOx阴极为CO2电解提供了更好的性能和耐用性.
- 这种表面后处理策略为定制矿氧化物阴极提供了洞察力.
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