一场黄金热:设计水凝用于含有混合金属离子的废水中选择性回收
Pamela Cinfrignini1,2, Alice Boschetti1,3, Giacomo Ghini4
1European Laboratory for Non-Linear Spectroscopy (LENS), Via Nello Carrara 1, 50019 Sesto Fiorentino, Italy.
ACS applied materials & interfaces
|November 25, 2024
概括
本研究介绍了聚烯胺-协同烯酸) 水凝,用于有效地从工业废水中回收黄金. 这些新型吸附剂有选择性地捕获和减少黄金,为贵金属回收利用提供了可持续的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 合成水凝为废水处理提供可扩展的解决方案.
- 有效地去除和回收重金属,特别是黄金,对于环境保护和资源回收至关重要.
- 现有的黄金回收方法通常依赖于弱相互作用或复杂的形成,需要替代方法.
研究的目的:
- 开发和评估易于制造的聚烯胺-联合烯酸) 水凝,用于选择性黄金回收.
- 为了研究水凝能够将黄金缩成元素纳米粒子和微粒子的能力.
- 评估水凝在含有其他贵金属的复杂工业废水矩阵中的性能.
主要方法:
- 合成聚烯胺-协同烯酸) 水凝.
- 批量吸附试验以确定黄金吸附能力.
- 分析将黄金降解为元素形式 (纳米粒子和微粒子).
- 与其他贵金属离子 (Ru,Ir,Pd,Pt,Rh) 进行竞争性吸附研究.
主要成果:
- 这些水凝显示出高吸附金的能力,高达124mg/g.
- 实现了黄金与其他贵金属离子的选择性分离.
- 黄金阳离子被成功地减少到元素黄金纳米粒子和微粒子.
- 该过程在室温的酸性环境中有效运行.
结论:
- 聚烯胺-联合烯酸) 水凝是从工业废水中回收黄金的有效和选择性吸附剂.
- 这种方法通过减少提供了一条新的黄金回收途径,避免复杂化或弱相互作用.
- 这些水凝显示出从各种复杂的金属溶液中回收黄金的潜力,包括电子废弃物水.
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