相关实验视频

Updated: Jun 6, 2025

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
08:46

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI

Published on: November 22, 2016

7.7K

从一个P-桥梁甲基到μ-Phosphinidenide和μ-Diphosphaurea单位在一个Dinickel核心

Roland A Schulz1, Uhut S Karaca2, Martin Diefenbach2,3

  • 1Universität Göttingen, Institut für Anorganische Chemie, Tammannstrasse 4, D-37077, Göttingen, Germany.

Chemistry (Weinheim an der Bergstrasse, Germany)
|November 25, 2024
PubMed
概括

这项研究探讨了新的dinickel (II) 复合物与桥接酸酸盐和酸连接物. 研究人员研究了反应机制和电子结构,揭示了这些有机金属化合物的新型结合模式和反应途径.

关键词:
这是一种NHC-phosphinidenide.酸化的使用方法双核复合体是二核复合体.这是一种二酸酸盐.酸乙烯酸是一种酸.

更多相关视频

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus14:07

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus

Published on: October 3, 2014

13.6K
The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes10:51

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

12.1K

相关概念视频

Hybridization of Atomic Orbitals II03:35

Hybridization of Atomic Orbitals II

sp3d and sp3d 2 Hybridization
31.8K
Diels–Alder Reaction Forming Bridged Bicyclic Products: Stereochemistry01:29

Diels–Alder Reaction Forming Bridged Bicyclic Products: Stereochemistry

Diels–Alder reactions between cyclic dienes locked in an s-cis configuration and dienophiles yield bridged bicyclic products.
4.6K
Aldehydes and Ketones to Alkenes: Wittig Reaction Mechanism01:14

Aldehydes and Ketones to Alkenes: Wittig Reaction Mechanism

The Wittig reaction, which converts aldehydes or ketones to alkenes using phosphorus ylides, proceeds through a nucleophilic addition‒elimination process.
The reaction begins with the nucleophilic addition between a phosphorus ylide and the carbonyl compound. Due to its carbanionic character,  phosphorus ylide acts as a strong nucleophile and attacks the electrophilic carbonyl group. This generates a charge-separated dipolar intermediate called betaine. The negatively charged oxygen atom and...
3.3K
[4+2] Cycloaddition of Conjugated Dienes: Diels–Alder Reaction01:16

[4+2] Cycloaddition of Conjugated Dienes: Diels–Alder Reaction

The Diels–Alder reaction is an example of a thermal pericyclic reaction between a conjugated diene and an alkene or alkyne, commonly referred to as a dienophile. The reaction involves a concerted movement of six π electrons, four from the diene and two from the dienophile, forming an unsaturated six-membered ring. As a result, these reactions are classified as [4+2] cycloadditions.
10.1K