用线性聚氨修饰剂对聚氨3-基酸盐进行修改,以及有机纳米填充剂-制剂和结构-性质关系
Iwona Zarzyka1, Beata Krzykowska1, Karol Hęclik2
1Department of Organic Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Powstancow Warszawy 6, 35959 Rzeszow, Poland.
Materials (Basel, Switzerland)
|November 27, 2024
概括
这项研究开发了使用聚氨和纳米粘土的新型聚3-基酸盐 (P3HB) 纳米生物复合材料. 这些环保材料为园艺和农业的应用提供了改进的加工和机械性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 纳米技术纳米技术
背景情况:
- 对聚烯 (PP) 产品日益增长的需求造成了不可生物降解的废物和环境问题.
- 合成聚合物依赖于不可再生的石化原料,导致环境退化.
- 生物聚合物,如聚3-基酸盐 (P3HB),提供可持续的替代品,其性能与PP相似.
研究的目的:
- 开发基于P3HB的混合聚合物纳米生物复合材料.
- 通过添加聚氨 (PU) 和Cloisite®30B.B.来增强P3HB的加工和操作特性.
- 研究由此产生的纳米生物复合材料的兼容性,形态学和机械性能.
主要方法:
- 挤出过程生产混合纳米生物复合材料.
- 福里埃变换红外光谱 (FTIR) 用于组件相互作用分析.
- 小角度X射线散射 (SAXS) 用于纳米和微观结构.
- 扫描电子显微镜 (SEM) 用于形态学.
- 硬度和抗拉强度的确定.
主要成果:
- 引入PU和Cloisite®30B有利地影响了加工,将挤出温度降低了10°C以上.
- FTIR证实了P3HB,PU和Cloisite®30B之间的兼容性,最佳兼容性在3%的Cloisite30B.
- 添加PU使材料弹性化,但降低了强度和柔性.
- 纳米粘土的添加增强了纳米生物复合材料的机械性能.
结论:
- 开发了基于P3HB的纳米生物复合材料,具有改进的加工和机械特性.
- PU和Cloisite®30B的组合提供了一个可行的途径来定制P3HB属性.
- 这些纳米生物复合材料显示出在园艺和农业中短期应用的潜力.
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