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修改了基化基基化的棉布的阻燃性研究2
Lingling Guo1, Hongqin Lin1, Zhenming Qi1
1College of Textile and Clothing, Yancheng Institute of Technology, Yancheng 224051, China.
Molecules (Basel, Switzerland)
|November 27, 2024
概括
这项研究提出了一种新的,环保的方法,利用硫化棉织物和离子制造可回收的阻燃棉织物. 经过处理的织物具有出色的耐火性,并保持了关键材料特性.
科学领域:
- 材料科学 材料科学 材料科学
- 织品化学 织品化学
- 聚合物化学 聚合物化学
背景情况:
- 传统的阻燃处理通常涉及危险化学品,缺乏耐用性.
- 开发可持续和可回收的阻燃织品对于安全和环境问题至关重要.
- 棉织物需要有效的处理来增强其耐火性,以更广泛的应用.
研究的目的:
- 开发一种简单,绿色和可回收的方法来生产阻燃棉织物.
- 用化学方法对棉织物进行改造,以提高其热稳定性和耐火性.
- 为了研究涉及硫棉和离子的阻燃机制.
主要方法:
- 使用 sodium periodate 氧化棉织物以创建活性位点.
- 氧化棉织物的硫化与二硫酸.
- 在硫化棉织物 (COT-SC-Ba) 上化离子 (Ba2+).
主要成果:
- 在COT-SC-Ba中,被证明具有延迟点火和降低热释放率 (HRR),总烟雾释放率 (TSR) 和有效燃烧热量 (EHC) 的非易燃性.
- 热重力测量分析 (TG/DTG) 显示热稳定性和焦炭形成增加,剩余质量显著增加.
- 34.4%的高限氧指数 (LOI) 和成功的垂直燃烧试验证实了出色的阻燃性,在洗和重新处理后可以恢复.
结论:
- 硫酸组和离子的组合有效地提高棉织物的阻燃性,通过促进焦炭层.
- 开发的方法简单,环保,并产生可回收的阻燃织品.
- 该工艺保持了可接受的破裂强度,白度和高度水平,使其适合实际应用.
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