木材的和易斯酸提取产生高品质的红素
Theodora E Leventis1, Patrick Judge2, Jialiang Zhang2
1The University of Iowa, Iowa City, Iowa 52242-1002, United States.
概括
这项研究介绍了易斯酸酸方法用于基纤维素分离,产生高质量的基因与低凝结. 这种方法增强了红素.
科学领域:
- 生物质的价值化 生物质的价值化
- 绿色化学 绿色化学
背景情况:
- 纤维素分离成素,纤维素和半纤维素是具有挑战性的.
- 素是一种未充分利用的,有价值的原料,这是由于其在低修饰下隔离的困难造成的.
- 开发高效的素提取方法对于可持续的化学工业至关重要.
研究的目的:
- 为了研究由酸易斯酸介导的纤维素分离获得的富含素的固体的特性.
- 评估酸易斯酸提取在保护红素原生结构方面的有效性.
- 评估木质素作为化学脱聚合物的原料的潜力.
主要方法:
- 和易斯酸介导的基纤维素分离.
- 剩余碳水化合物的分析.
- 脱聚合效率研究.
- 异核单量子相干 (HSQC) 和固态核磁共振 (NMR) 谱学.
- 与替代性红素来源进行基准测试.
主要成果:
- 和易斯酸提取取出80-85%的碳水化合物.
- 由此产生的木素表现出较低的凝结率和与原生木素的高度结构相似性.
- 白松木质素的脱聚合产生了47%的可提取单体,与最先进的方法相美.
- 在老化或度方面,木线素表现出不稳定性,归因于介导的脱甲基化.
结论:
- 酸易斯酸提取是一种有效的方法,可以从纤维素酸中获得低凝聚率的红素.
- 木质素作为一种有价值的原料显示出前景,尽管稳定性问题需要进一步调查.
- 这种方法为增加生物炼油厂中素利用提供了一条途径.
相关概念视频
Extraction: Advanced Methods
420
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
420
Alcohols from Carbonyl Compounds: Reduction
10.2K
Reduction is a simple strategy to convert a carbonyl group to a hydroxyl group. The three major pathways to reduce carbonyls to alcohols are catalytic hydrogenation, hydride reduction, and borane reduction.
Catalytic hydrogenation is similar to the reduction of an alkene or alkyne by adding H2 across the pi bond in the presence of transition metal catalysts like Raney Ni, Pd–C, Pt, or Ru. Aldehydes and ketones can be reduced by this method, often under mild to moderate heat (25–100°C) and...
Catalytic hydrogenation is similar to the reduction of an alkene or alkyne by adding H2 across the pi bond in the presence of transition metal catalysts like Raney Ni, Pd–C, Pt, or Ru. Aldehydes and ketones can be reduced by this method, often under mild to moderate heat (25–100°C) and...
10.2K
Hydroboration-Oxidation of Alkenes
7.9K
In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
7.9K
Lewis Acids and Bases
43.5K
In 1923, G. N. Lewis proposed a generalized definition of acid-base behavior in which acids and bases are identified by their ability to accept or to donate a pair of electrons and form a coordinate covalent bond.
A coordinate covalent bond (or dative bond) occurs when one of the atoms in the bond provides both bonding electrons. For example, a coordinate covalent bond occurs when a water molecule combines with a hydrogen ion to form a hydronium ion. A coordinate covalent bond also results when...
A coordinate covalent bond (or dative bond) occurs when one of the atoms in the bond provides both bonding electrons. For example, a coordinate covalent bond occurs when a water molecule combines with a hydrogen ion to form a hydronium ion. A coordinate covalent bond also results when...
43.5K
Preparation of Alcohols via Addition Reactions
6.1K
Overview
The acid-catalyzed addition of water to the double bond of alkenes is a large-scale industrial method used to synthesize low-molecular-weight alcohols. An acidic atmosphere is required to allow the hydrogen in the water molecule to act as an electrophile and attack the double bond in an alkene. The addition of a proton to the double bond creates a carbocation intermediate. The proton preferentially bonds to the less substituted end of the double bond to create a more stable carbocation...
The acid-catalyzed addition of water to the double bond of alkenes is a large-scale industrial method used to synthesize low-molecular-weight alcohols. An acidic atmosphere is required to allow the hydrogen in the water molecule to act as an electrophile and attack the double bond in an alkene. The addition of a proton to the double bond creates a carbocation intermediate. The proton preferentially bonds to the less substituted end of the double bond to create a more stable carbocation...
6.1K
Sample Preparation for Analysis: Advanced Techniques
301
Accurate analysis of complex samples often requires advanced preparation techniques to achieve reliable and reproducible results. Samples containing inorganic or organic materials can be challenging to dissolve or decompose effectively. Standard sample preparation methods include acid digestion, fusion, dry ashing, and wet digestion.
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
301


